Wang Yang, Del Rosal Iker, Qin Guorui, Zhao Lanxiao, Maron Laurent, Shi Xianghui, Cheng Jianhua
State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, No. 5625, Renmin Street, Changchun 130022, China.
Chem Commun (Camb). 2021 Aug 14;57(63):7766-7769. doi: 10.1039/d1cc01841h. Epub 2021 Jul 14.
Hydrogenolysis of the half-sandwich penta-arylcycopentadienyl-supported rare-earth metal dibenzyl complexes [(Cp)Ln(p-CH-CH-Me)(THF)] (Cp = CAr, Ar = 3,5-Pr-CH; Ln = Sc, La) afforded a bimetallic scandium complex [(Cp)Sc(H)(μ-OCH)] (2) with two terminal hydrido ligands, and a double-sandwich bimetallic lanthanum hydride complex [(Cp)La(μ-H)] (4) bearing the reduced Cp ligand. DFT calculations were conducted to elucidate the reaction profiles.
半夹心五芳基环戊二烯基支撑的稀土金属二苄基配合物[(Cp)Ln(p-CH-CH-Me)(THF)]（Cp = CAr，Ar = 3,5-Pr-CH；Ln = Sc，La）的氢解反应得到了一种带有两个末端氢配体的双金属钪配合物[(Cp)Sc(H)(μ-OCH)]（2），以及一种带有还原Cp配体的双夹心双金属镧氢配合物[(Cp)La(μ-H)]（4）。进行了密度泛函理论计算以阐明反应过程。
