Engineered polyethersulfone membrane for well-dispersed silver nanoparticle impregnation at high loading: high water permeate flux and biofouling prevention.

We present a new method for impregnation of silver nanoparticles (Ag NPs) at high loading on polyethersulfone (PES) membrane's external surface, simultaneously retaining native membrane's porosity - to achieve a high water permeate flux without biofouling. This was possible by PES membrane's surface modification with acrylic acid (AA), finally leading to AA-Ag-PES membrane. AA-Ag-PES had a high (9.04%) Ag-NP loading selectively on membrane surface, as discrete, smaller (mean size: 20 nm) nanoparticles (NPs). In nonfunctionalized Ag-PES, aggregated (mean size: 70 nm) NPs, with lower Ag loading (0.73 wt.%) was obtained, with NP being present both on membrane surface and inside pores. Consequently, AA-Ag-PES could maintain similar water permeability and porosity (10,153.05 Lm hbar and 69.98%, respectively), as in native PES (11,368.74 Lm hbar and 68.86%, respectively); whereas both parameters dropped significantly for Ag-PES (4,869.66 Lm hbar and 49.02%, respectively). AA-Ag-PES also showed least flux reduction (7.7%) due to its anti-biofouling property and high flux recovery after usage and cleaning, compared to native PES and Ag-PES membrane's much higher flux reduction (54.29% and 36.7%, respectively). Hence, discrete NP impregnation, avoiding pore blockage, is key for achieving high water flux and anti-biofouling properties (in AA-Ag-PES), compared to non-functionalized Ag-PES, due to aggregated Ag-NPs inside its pores.