Formation of the Inorganic and Organic Shells on the Surface of CdSe Quantum Dots.

Embedding quantum dots (QDs) into an organic matrix of controllable order requires the identification of their structural characteristics. This analysis is necessary for the creation of anisotropic composites that are sensitive to external stimuli. We have studied the QD structures formed during the single-step synthesis of CdSe/ZnS QDs and their transformations after the initial ligand's substitution for another ligand. This single-step process leads to the formation of the core/shell structure. We detect the presence of two oleic acid residues ionically connected to Zn and Cd. At the same time, the amount of Cd oleate at the surface is very small. We observe the ligand exchange process at the surface of the core/shell QDs. The oleic acid residues are substituted by terphenyl-containing (TERPh-COOH) aromatic acid residues. The reaction between CdSe/ZnS carrying TOP and oleic acid residues ionically bound with QDs and terphenyl-containing acid leads to the coexistence of multiple ligands on the QD surface at a ratio of 11:6:33 for TOP/OA/TERPh-COOH.