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3D打印一种用于海水淡化和农业应用中消除盐分积累的仿生桥拱太阳能蒸发器。

3D Printing a Biomimetic Bridge-Arch Solar Evaporator for Eliminating Salt Accumulation with Desalination and Agricultural Applications.

作者信息

Zou Miaomiao, Zhang Yu, Cai Zheren, Li Chuxin, Sun Zhiyuan, Yu Cunlong, Dong Zhichao, Wu Lei, Song Yanlin

机构信息

Key Laboratory of Green Printing, Beijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, P. R. China.

University of Chinese Academy of Sciences, Beijing, 100049, P. R. China.

出版信息

Adv Mater. 2021 Aug;33(34):e2102443. doi: 10.1002/adma.202102443. Epub 2021 Jul 19.

Abstract

Solar-driven water evaporation has been considered a sustainable method to obtain clean water through desalination. However, its further application is limited by the complicated preparation strategy, poor salt rejection, and durability. Herein, inspired by superfast water transportation of the Nepenthes alata peristome surface and continuous bridge-arch design in architecture, a biomimetic 3D bridge-arch solar evaporator is proposed to induce Marangoni flow for long-term salt rejection. The formed double-layer 3D liquid film on the evaporator is composed of a confined water film for water supplementation and a free-flowing water film with ultrafast directional Marangoni convection for salt rejection, which functions cooperatively to endow the 3D evaporator with all-in-one function including superior solar-driven water evaporation (1.64 kg m h , 91% efficiency for pure water), efficient solar desalination, and long-term salt-rejecting property (continuous 200 h in 10 wt% saline water) without any post-cleaning treatment. The design principle of the 3D structures is provided for extending the application of Marangoni-driven salt rejection and the investigation of structure-design-induced liquid film control in the solar desalination field. Furthermore, excellent mechanical and chemical stability is proved, where a self-sustainable and solar-powered desalination-cultivation platform is developed, indicating promising application for agricultural cultivation.

摘要

太阳能驱动的水蒸发被认为是一种通过海水淡化获取清洁水的可持续方法。然而,其进一步应用受到复杂的制备策略、较差的脱盐性能和耐久性的限制。在此,受猪笼草口缘表面超快水传输和建筑中连续桥拱设计的启发,提出了一种仿生三维桥拱太阳能蒸发器,以诱导马兰戈尼流实现长期脱盐。蒸发器上形成的双层三维液膜由用于补水的受限水膜和具有超快定向马兰戈尼对流的自由流动水膜组成,用于脱盐,二者协同作用赋予三维蒸发器一体化功能,包括优异的太阳能驱动水蒸发(1.64 kg m² h⁻¹,纯水效率91%)、高效太阳能海水淡化和长期脱盐性能(在10 wt%盐水中连续运行200小时),无需任何后处理清洗。提供了三维结构的设计原理,以扩展马兰戈尼驱动脱盐的应用,并研究太阳能海水淡化领域中结构设计引起的液膜控制。此外,还证明了其优异的机械和化学稳定性,开发了一个自我维持的太阳能海水淡化-种植平台,显示出在农业种植方面的应用前景。

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