• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

用于海洋防污应用的聚二甲基硅氧烷和聚氨酯共混膜的简易制备方法

Simple Preparation of Polydimethylsiloxane and Polyurethane Blend Film for Marine Antibiofouling Application.

作者信息

Chungprempree Jirasuta, Charoenpongpool Sutep, Preechawong Jitima, Atthi Nithi, Nithitanakul Manit

机构信息

The Petroleum and Petrochemical College, Chulalongkorn University, Chula Soi 12, Wangmai Pathumwan, Bangkok 10330, Thailand.

Center of Excellence on Petrochemical and Materials Technology, Chula Soi 12, Wangmai Pathumwan, Bangkok 10330, Thailand.

出版信息

Polymers (Basel). 2021 Jul 8;13(14):2242. doi: 10.3390/polym13142242.

DOI:10.3390/polym13142242
PMID:34301003
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC8309381/
Abstract

A key way to prevent undesirable fouling of any structure in the marine environment, without harming any microorganisms, is to use a polymer film with high hydrophobicity. The polymer film, which was simply prepared from a blend of hydrophobic polydimethylsiloxane elastomer and hydrophilic polyurethane, showed improved properties and economic viability for antifouling film for the marine industry. The field emission scanning electron microscope and energy dispersive X-ray spectrometer (FESEM and EDX) results from the polymer blend suggested a homogenous morphology and good distribution of the polyurethane disperse phase. The PDMS:PU blend (95:5) film gave a water contact angle of 103.4° ± 3.8° and the PDMS film gave a water contact angle of 109.5° ± 4.2°. Moreover, the PDMS:PU blend (95:5) film could also be modified with surface patterning by using soft lithography process to further increase the hydrophobicity. It was found that PDMS:PU blend (95:5) film with micro patterning from soft lithography process increased the contact angle to 128.8° ± 1.6°. The results from a field test in the Gulf of Thailand illustrated that the bonding strength between the barnacles and the PDMS:PU blend (95:5) film (0.07 MPa) were lower than the bonding strength between the barnacles and the carbon steel (1.16 MPa). The barnacles on the PDMS:PU blend (95:5) film were more easily removed from the surface. This indicated that the PDMS:PU blend (95:5) exhibited excellent antifouling properties and the results indicated that the PDMS:PU blend (95:5) film with micro patterning surface could be employed for antifouling application.

摘要

在不伤害任何微生物的情况下，防止海洋环境中任何结构出现不良污垢的一个关键方法是使用具有高疏水性的聚合物薄膜。这种聚合物薄膜由疏水性聚二甲基硅氧烷弹性体和亲水性聚氨酯的混合物简单制备而成，对于海洋工业用防污薄膜而言，它展现出了更好的性能和经济可行性。聚合物共混物的场发射扫描电子显微镜和能量色散X射线光谱仪（FESEM和EDX）结果表明，聚氨酯分散相具有均匀的形态和良好的分布。PDMS:PU共混物（95:5）薄膜的水接触角为103.4°±3.8°，PDMS薄膜的水接触角为109.5°±4.2°。此外，PDMS:PU共混物（95:5）薄膜还可以通过软光刻工艺进行表面图案化修饰，以进一步提高疏水性。研究发现，采用软光刻工艺形成微图案的PDMS:PU共混物（95:5）薄膜将接触角提高到了128.8°±1.6°。在泰国湾进行的现场测试结果表明，藤壶与PDMS:PU共混物（95:5）薄膜之间的粘结强度（0.07 MPa）低于藤壶与碳钢之间的粘结强度（1.16 MPa）。PDMS:PU共混物（95:5）薄膜上的藤壶更容易从表面去除。这表明PDMS:PU共混物（95:5）具有优异的防污性能，结果表明具有微图案表面的PDMS:PU共混物（95:5）薄膜可用于防污应用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1396/8309381/1386752460a9/polymers-13-02242-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1396/8309381/4b3aaac13b98/polymers-13-02242-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1396/8309381/6288a50ad9e5/polymers-13-02242-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1396/8309381/59d579914547/polymers-13-02242-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1396/8309381/e2eb8868758f/polymers-13-02242-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1396/8309381/6e1a38b86985/polymers-13-02242-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1396/8309381/21cb3c51644a/polymers-13-02242-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1396/8309381/252da9faf18d/polymers-13-02242-g007a.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1396/8309381/c79d5b7efa29/polymers-13-02242-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1396/8309381/9cdb6adc76ce/polymers-13-02242-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1396/8309381/6f3e01dca173/polymers-13-02242-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1396/8309381/91d81ad9ede2/polymers-13-02242-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1396/8309381/1386752460a9/polymers-13-02242-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1396/8309381/4b3aaac13b98/polymers-13-02242-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1396/8309381/6288a50ad9e5/polymers-13-02242-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1396/8309381/59d579914547/polymers-13-02242-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1396/8309381/e2eb8868758f/polymers-13-02242-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1396/8309381/6e1a38b86985/polymers-13-02242-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1396/8309381/21cb3c51644a/polymers-13-02242-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1396/8309381/252da9faf18d/polymers-13-02242-g007a.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1396/8309381/c79d5b7efa29/polymers-13-02242-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1396/8309381/9cdb6adc76ce/polymers-13-02242-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1396/8309381/6f3e01dca173/polymers-13-02242-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1396/8309381/91d81ad9ede2/polymers-13-02242-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1396/8309381/1386752460a9/polymers-13-02242-g012.jpg

相似文献

1
Simple Preparation of Polydimethylsiloxane and Polyurethane Blend Film for Marine Antibiofouling Application.用于海洋防污应用的聚二甲基硅氧烷和聚氨酯共混膜的简易制备方法
Polymers (Basel). 2021 Jul 8;13(14):2242. doi: 10.3390/polym13142242.
2
Developing an Effective and Durable Film for Marine Fouling Prevention from PDMS/SiO and PDMS/PU with SiO Composites.利用含二氧化硅复合材料的聚二甲基硅氧烷/二氧化硅（PDMS/SiO）和聚二甲基硅氧烷/聚氨酯（PDMS/PU）开发一种用于防止海洋生物污损的高效耐用薄膜。
Polymers (Basel). 2022 Oct 11;14(20):4252. doi: 10.3390/polym14204252.
3
Squid inspired elastomer marine coating with efficient antifouling strategies: Hydrophilized defensive surface and lower modulus.鱿鱼启发的弹性体海洋涂层具有高效的防污策略：亲水防御表面和较低的模量。
Colloids Surf B Biointerfaces. 2022 May;213:112392. doi: 10.1016/j.colsurfb.2022.112392. Epub 2022 Feb 3.
4
The Effects of Solvent on Superhydrophobic Polyurethane Coating Incorporated with Hydrophilic SiO Nanoparticles as Antifouling Paint.溶剂对掺入亲水性SiO纳米颗粒作为防污涂料的超疏水聚氨酯涂层的影响。
Polymers (Basel). 2023 Mar 7;15(6):1328. doi: 10.3390/polym15061328.
5
Creating superhydrophobic, abrasion-resistant and breathable coatings from water-borne polydimethylsiloxane-polyurethane Co-polymer and fumed silica.利用水性聚二甲基硅氧烷 - 聚氨酯共聚物和气相二氧化硅制备超疏水、耐磨且透气的涂层。
J Colloid Interface Sci. 2021 Aug 15;596:479-492. doi: 10.1016/j.jcis.2021.02.072. Epub 2021 Mar 2.
6
Silicone Elastomer with Self-Generating Zwitterions for Antifouling Coatings.具有自产生两性离子的硅酮弹性体用于防污涂料。
Langmuir. 2021 Jul 13;37(27):8253-8260. doi: 10.1021/acs.langmuir.1c00984. Epub 2021 Jun 30.
7
Response Surface Optimisation of Polydimethylsiloxane (PDMS) on Borosilicate Glass and Stainless Steel (SS316) to Increase Hydrophobicity.聚二甲基硅氧烷（PDMS）在硼硅酸盐玻璃和不锈钢（SS316）上的响应面优化以增加疏水性。
Molecules. 2022 May 25;27(11):3388. doi: 10.3390/molecules27113388.
8
Preparation and Properties of Fluorosilicone Fouling-Release Coatings.氟硅氧烷防污涂料的制备与性能
Polymers (Basel). 2022 Sep 11;14(18):3804. doi: 10.3390/polym14183804.
9
Construction of Durable Self-Cleaning PDMS Film on Polyester Fabric Surface.在聚酯织物表面构建耐用的自清洁聚二甲基硅氧烷薄膜。
Materials (Basel). 2022 Dec 21;16(1):52. doi: 10.3390/ma16010052.
10
Preparation and Antifouling Property of Polyurethane Film Modified by PHMG and HA Using Layer-by-Layer Assembly.采用层层组装法制备的聚六亚甲基胍和透明质酸改性聚氨酯薄膜及其防污性能
Polymers (Basel). 2021 Mar 18;13(6):934. doi: 10.3390/polym13060934.

引用本文的文献

1
Design and development of a novel polymer coating system with exceptional creep resistance.具有卓越抗蠕变性的新型聚合物涂层系统的设计与开发。
Npj Mater Sustain. 2025;3(1):21. doi: 10.1038/s44296-025-00063-x. Epub 2025 Jun 30.
2
Thermodynamic Parameters of Crosslinked Elastomers (BR, SBR and NBR) and Their Blends.交联弹性体（顺丁橡胶、丁苯橡胶和丁腈橡胶）及其共混物的热力学参数
Polymers (Basel). 2024 Jan 28;16(3):351. doi: 10.3390/polym16030351.
3
Developing an Effective and Durable Film for Marine Fouling Prevention from PDMS/SiO and PDMS/PU with SiO Composites.

本文引用的文献

1
Superhydrophobic lotus-leaf-like surface made from reduced graphene oxide through soft-lithographic duplication.通过软光刻复制由还原氧化石墨烯制成的超疏水荷叶状表面。
RSC Adv. 2020 Feb 3;10(9):5478-5486. doi: 10.1039/c9ra10373b. eCollection 2020 Jan 29.
2
A Review of Polysiloxanes in Terms of Their Application in Explosives.聚硅氧烷在炸药中的应用综述
Polymers (Basel). 2021 Mar 29;13(7):1080. doi: 10.3390/polym13071080.
3
Non-toxic, non-biocide-release antifouling coatings based on molecular structure design for marine applications.
利用含二氧化硅复合材料的聚二甲基硅氧烷/二氧化硅（PDMS/SiO）和聚二甲基硅氧烷/聚氨酯（PDMS/PU）开发一种用于防止海洋生物污损的高效耐用薄膜。
Polymers (Basel). 2022 Oct 11;14(20):4252. doi: 10.3390/polym14204252.
4
Study on the Physical, Thermal and Mechanical Properties of SEBS/PP (Styrene-Ethylene-Butylene-Styrene/Polypropylene) Blend as a Medical Fluid Bag.作为医用液体袋的SEBS/PP（苯乙烯-乙烯-丁烯-苯乙烯/聚丙烯）共混物的物理、热学和力学性能研究
Polymers (Basel). 2022 Aug 11;14(16):3267. doi: 10.3390/polym14163267.
基于分子结构设计的用于海洋应用的无毒、无生物ocide释放的防污涂料。 （注：原文中“biocide”可能有误，推测为“biocide-release”表述不太准确，若为“biocide-free”更合适，准确译文为“基于分子结构设计的用于海洋应用的无毒、无释放杀生剂的防污涂料” ）
J Mater Chem B. 2015 Aug 28;3(32):6547-6570. doi: 10.1039/c5tb00232j. Epub 2015 Jul 8.
4
Influence of hydroxyl-terminated polydimethylsiloxane on high-strength biocompatible polycarbonate urethane films.端羟基聚二甲基硅氧烷对高强度生物相容性聚碳酸酯聚氨酯薄膜的影响。
Biomed Mater. 2016 Dec 9;12(1):015011. doi: 10.1088/1748-605X/12/1/015011.
5
Poly[3,4-ethylene dioxythiophene (EDOT) -co- 1,3,5-tri[2-(3,4-ethylene dioxythienyl)]-benzene (EPh)] copolymers (PEDOT-co-EPh): optical, electrochemical and mechanical properties.聚[3,4-乙撑二氧噻吩（EDOT）-co-1,3,5-三[2-(3,4-乙撑二氧噻吩基)]-苯（EPh）]共聚物（PEDOT-co-EPh）：光学、电化学和机械性能
J Mater Chem B. 2015 Jul 7;3(25):5010-5020. doi: 10.1039/C5TB00053J.
6
The effects of polydimethylsiloxane on transparent and hydrophobic waterborne polyurethane coatings containing polydimethylsiloxane.含有聚二甲基硅氧烷的透明疏水性水性聚氨酯涂料中聚二甲基硅氧烷的影响。
Phys Chem Chem Phys. 2014 Apr 14;16(14):6787-94. doi: 10.1039/c3cp54429j. Epub 2014 Mar 5.
7
Toxicity of copper oxide nanoparticles in the blue mussel, Mytilus edulis: a redox proteomic investigation.氧化铜纳米颗粒对贻贝（Mytilus edulis）的毒性：氧化还原蛋白质组学研究。
Chemosphere. 2014 Aug;108:289-99. doi: 10.1016/j.chemosphere.2014.01.054. Epub 2014 Feb 26.
8
A comparison of the antifouling/foul-release characteristics of non-biocidal xerogel and commercial coatings toward micro- and macrofouling organisms.无生物杀灭剂水凝胶与商品化涂层的防污/自洁特性比较：针对微、宏观污损生物。
Biofouling. 2012;28(5):511-23. doi: 10.1080/08927014.2012.690197.
9
Accumulation and toxicity of copper oxide nanoparticles in the digestive gland of Mytilus galloprovincialis.铜氧化纳米颗粒在贻贝消化腺中的积累和毒性。
Aquat Toxicol. 2012 Aug 15;118-119:72-79. doi: 10.1016/j.aquatox.2012.03.017. Epub 2012 Apr 3.
10
Antimicrobial strategies effective against infectious bacterial biofilms.抗微生物策略有效对抗感染性细菌生物膜。
Curr Med Chem. 2011;18(14):2129-45. doi: 10.2174/092986711795656216.