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废弃聚氨酯/苯乙烯-丁二烯-苯乙烯复合改性沥青的性能及微观特性评价

Evaluation of Properties and Micro-Characteristics of Waste Polyurethane/Styrene-Butadiene-Styrene Composite Modified Asphalt.

作者信息

Chen Bei, Dong Fuqiang, Yu Xin, Zheng Changjiang

机构信息

College of Civil and Transportation Engineering, Hohai University, Nanjing 210098, China.

出版信息

Polymers (Basel). 2021 Jul 9;13(14):2249. doi: 10.3390/polym13142249.

Abstract

In order to solve the problems caused by asphalt diseases and prolong the life cycle of asphalt pavement, many studies on the properties of modified asphalt have been conducted, especially polyurethane (PU) modified asphalt. This study is to replace part of the styrene-butadiene-styrene (SBS) modifier with waste polyurethane (WP), for preparing WP/SBS composite modified asphalt, as well as exploring its properties and microstructure. On this basis, this paper studied the basic performance of WP/SBS composite modified asphalt with a conventional performance test, to analyze the high- and low-temperature rheological properties, permanent deformation resistance and storage stability of WP/SBS composite modified asphalt by dynamic shear rheometer (DSR) and bending beam rheometer (BBR) tests. The microstructure of WP/SBS composite modified asphalt was also observed by fluorescence microscope (FM) and Fourier transform infrared spectroscopy (FTIR), as well as the reaction between WP and asphalt. According to the results of this study, WP can replace SBS as a modifier to prepare WP/SBS composite modified asphalt with good low-temperature resistance, whose high-temperature performance will be lower than that of SBS modified asphalt. After comprehensive consideration, 4% SBS content and 15% WPU content (4 S/15 W) are determined as the suitable types of WPU/SBS composite modified asphalt.

摘要

为了解决沥青病害带来的问题并延长沥青路面的生命周期,人们对改性沥青的性能进行了大量研究,尤其是聚氨酯(PU)改性沥青。本研究旨在用废弃聚氨酯(WP)替代部分苯乙烯-丁二烯-苯乙烯(SBS)改性剂,制备WP/SBS复合改性沥青,并探究其性能和微观结构。在此基础上,本文通过常规性能试验研究了WP/SBS复合改性沥青的基本性能,利用动态剪切流变仪(DSR)和弯曲梁流变仪(BBR)试验分析了WP/SBS复合改性沥青的高低温流变性能、抗永久变形性能和储存稳定性。还通过荧光显微镜(FM)和傅里叶变换红外光谱(FTIR)观察了WP/SBS复合改性沥青的微观结构以及WP与沥青之间的反应。根据本研究结果,WP可替代SBS作为改性剂制备出具有良好低温抗性的WP/SBS复合改性沥青,但其高温性能低于SBS改性沥青。综合考虑后,确定4%的SBS含量和15%的WPU含量(4S/15W)为合适的WPU/SBS复合改性沥青类型。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6774/8309305/36127fbc77b2/polymers-13-02249-g001.jpg

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