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使用氧化锌修饰的复杂3D打印多孔结构量化即时水清洁效率。

Quantifying instant water cleaning efficiency using zinc oxide decorated complex 3D printed porous architectures.

作者信息

Kumbhakar Partha, Ambekar Rushikesh S, Mahapatra Preeti Lata, Sekhar Tiwary Chandra

机构信息

Metallurgical and Materials Engineering, Indian Institute of Technology Kharagpur, Kharagpur 721302, India.

School of Nano Science and Technology, Indian Institute of Technology, Kharagpur, West Bengal 721302, India.

出版信息

J Hazard Mater. 2021 Sep 15;418:126383. doi: 10.1016/j.jhazmat.2021.126383. Epub 2021 Jun 12.

Abstract

Industrialization harms the quality of water; therefore, cleaning and monitoring water sources are essential for sustainable human health and aquatic life. An increase in active surface area and porosity can result in quick and efficient cleaning activity. 3D printing can build porous architecture with controlled porosity and active surface area. Here, catalytically active ZnO nanosheets were grown on the surface of 3D printed architecture (Schwarzites and Weissmuller) with different porosity and surface area. The Weissmuller structure along with ZnO, has shown better catalytic performance due to its higher porosity (~69%) and high active surface area, compared to Schwarzites structure. Synergistic effect of adsorption and photodegradation has resulted in ~95% removal efficiency of mixed dye within 10 min by Weissmuller structure. The dye degradation efficiency was determined using colorimetric measurements with a regular smartphone for real-time quantitative investigation of dye removal efficiency. Most importantly, decorated 3D printed structures exhibit high structural stability without residuals (ZnO nanosheets) in water after performing the recycling experiment. Therefore, the decorated 3D printing structures and colorimetric detection method will offer a user-friendly versatile technique for analysis of removal efficiency of toxic components in different polluted water sources without using high-end sophisticated instruments and complicated procedures.

摘要

工业化会损害水质;因此,清洁和监测水源对于人类可持续健康和水生生物至关重要。活性表面积和孔隙率的增加可带来快速高效的清洁活动。3D打印能够构建具有可控孔隙率和活性表面积的多孔结构。在此,在具有不同孔隙率和表面积的3D打印结构(黑硅石和魏斯穆勒结构)表面生长了具有催化活性的ZnO纳米片。与黑硅石结构相比,魏斯穆勒结构与ZnO一起,因其更高的孔隙率(约69%)和高活性表面积而表现出更好的催化性能。吸附和光降解的协同作用使魏斯穆勒结构在10分钟内对混合染料的去除效率达到约95%。使用普通智能手机通过比色测量来测定染料降解效率,以实时定量研究染料去除效率。最重要的是,经过修饰的3D打印结构在进行循环实验后在水中表现出高结构稳定性且无残留(ZnO纳米片)。因此,经过修饰的3D打印结构和比色检测方法将提供一种用户友好的通用技术,无需使用高端精密仪器和复杂程序即可分析不同污染水源中有毒成分的去除效率。

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