• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

通过晶体溶剂解吸引发的具有氢键的二维钴（II）配合物的自旋转变

Spin transition triggered by desorption of crystal solvents for a two-dimensional cobalt(ii) complex with hydrogen bonding.

作者信息

Kanetomo Takuya, Inokuma Kiwamu, Naoi Yuya, Enomoto Masaya

机构信息

Department of Chemistry, Faculty of Science Division 1, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku-ku, Tokyo 162-8601, Japan.

出版信息

Dalton Trans. 2021 Aug 28;50(32):11243-11248. doi: 10.1039/d1dt01934a. Epub 2021 Aug 3.

DOI:10.1039/d1dt01934a
PMID:34341808
Abstract

Co(5tpybNOH) (1; 5tpybNOH = 5,5''-bis(N-tert-butyl hydroxylamino)-2,2':6',2''-terpyridine) has a two-dimensional (2D) structure through a hydrogen bond between the NOH sites, as revealed by X-ray crystallography. The crystal solvents were desorbed above 300 K as shown by thermal analyses and powder X-ray crystallography. The removal of the crystal solvents allowed irreversible structural changes and a spin transition of the Co centre from S = 1/2 to 3/2.

摘要

Co(5tpybNOH)（1；5tpybNOH = 5,5''-双（N-叔丁基羟胺基）-2,2':6',2''-三联吡啶）通过NOH位点之间的氢键具有二维（2D）结构，这由X射线晶体学揭示。热分析和粉末X射线晶体学表明，晶体溶剂在300 K以上解吸。晶体溶剂的去除导致不可逆的结构变化以及钴中心从S = 1/2到3/2的自旋转变。

相似文献

1
Spin transition triggered by desorption of crystal solvents for a two-dimensional cobalt(ii) complex with hydrogen bonding.通过晶体溶剂解吸引发的具有氢键的二维钴（II）配合物的自旋转变
Dalton Trans. 2021 Aug 28;50(32):11243-11248. doi: 10.1039/d1dt01934a. Epub 2021 Aug 3.
2
Water Molecule-Induced Reversible Magnetic Switching in a Bis-Terpyridine Cobalt(II) Complex Exhibiting Coexistence of Spin Crossover and Orbital Transition Behaviors.在一个同时展现自旋交叉和轨道跃迁行为的双吡啶钴（II）配合物中，水分子诱导的可逆磁开关效应
Inorg Chem. 2020 Dec 7;59(23):16843-16852. doi: 10.1021/acs.inorgchem.0c00818. Epub 2020 Oct 1.
3
Molecular and Electronic Structures of Homoleptic Six-Coordinate Cobalt(I) Complexes of 2,2':6',2″-Terpyridine, 2,2'-Bipyridine, and 1,10-Phenanthroline. An Experimental and Computational Study.2,2':6',2″-三联吡啶、2,2'-联吡啶和1,10-菲咯啉的均配六配位钴（I）配合物的分子结构与电子结构。一项实验与计算研究。
Inorg Chem. 2015 Dec 21;54(24):12002-18. doi: 10.1021/acs.inorgchem.5b02415. Epub 2015 Dec 4.
4
New anionic cobalt complexes using highly hindered bis-amides with varying donor abilities as ligands.使用具有不同给体能力的高度受阻双酰胺作为配体的新型阴离子钴配合物。
Dalton Trans. 2007 Jun 7(21):2135-44. doi: 10.1039/b617604f. Epub 2007 Apr 23.
5
Hydrogen bond-induced abrupt spin crossover behaviour in 1-D cobalt(II) complexes - the key role of solvate water molecules.一维钴（II）配合物中氢键诱导的突变自旋交叉行为——溶剂水分子的关键作用
Dalton Trans. 2021 Jun 8;50(22):7843-7853. doi: 10.1039/d1dt01069g.
6
Systematic study of spin crossover and structure in [Co(terpyRX)2](Y)2 systems (terpyRX = 4'-alkoxy-2,2':6',2''-terpyridine, X = 4, 8, 12, Y = BF4(-), ClO4(-), PF6(-), BPh4(-)).[Co(terpyRX)2](Y)2体系（terpyRX = 4'-烷氧基-2,2':6',2''-三联吡啶，X = 4, 8, 12，Y = BF4(-), ClO4(-), PF6(-), BPh4(-)）中自旋交叉和结构的系统研究
Inorg Chem. 2009 Aug 3;48(15):7033-47. doi: 10.1021/ic802252k.
7
Spin-crossover cobalt(II) complexes exhibiting temperature- and concentration-dependent optical changes in solution.在溶液中表现出温度和浓度依赖性光学变化的自旋交叉钴（II）配合物。
Dalton Trans. 2024 Jun 4;53(22):9547-9553. doi: 10.1039/d4dt00433g.
8
Unprecedented structural variations in trinuclear mixed valence Co(II/III) complexes: theoretical studies, pnicogen bonding interactions and catecholase-like activities.三核混合价态钴（II/III）配合物中前所未有的结构变化：理论研究、氮族元素键合相互作用及类儿茶酚酶活性
Dalton Trans. 2015 Feb 28;44(8):3862-76. doi: 10.1039/c4dt03446e.
9
One-, Two-, and Three-Dimensional Heterospin Complexes Consisting of 4-(N-tert-Butyloxylamino)pyridine (4NOpy), Dicyanamide Ion (DCA), and 3d Metal Ions: Crystal Structures and Magnetic Properties of [M(II)(4NOpy)x(DCA)y(CH3CN)z]n (M = Mn, Co, Ni, Cu, Zn).由4-(N-叔丁基氧代氨基)吡啶(4NOpy)、双氰胺离子(DCA)和3d金属离子组成的一维、二维和三维异自旋配合物：[M(II)(4NOpy)x(DCA)y(CH3CN)z]n (M = Mn、Co、Ni、Cu、Zn)的晶体结构和磁性
Inorg Chem. 2016 Jan 19;55(2):717-28. doi: 10.1021/acs.inorgchem.5b02159. Epub 2015 Dec 24.
10
Enhanced third-order nonlinear optical properties determined in thin films using the Z-scan technique: bis(μ-4,4'-oxydibenzoato)bis[(4'-phenyl-2,2':6',2''-terpyridine)cobalt(II)].使用Z扫描技术在薄膜中测定的增强型三阶非线性光学性质：双（μ-4,4'-氧化二苯甲酸根）双[（4'-苯基-2,2':6',2''-三联吡啶）钴（II）] 。
Acta Crystallogr C Struct Chem. 2016 May 1;72(Pt 5):451-5. doi: 10.1107/S2053229616006677. Epub 2016 Apr 25.

引用本文的文献

1
Metal-Dilution Effect on Spin Transition Behavior of Solvated/Desolvated Hydrogen-Bonded Cobalt(II)-Organic Frameworks.金属稀释对溶剂化/去溶剂化氢键钴（II）-有机框架自旋转变行为的影响
ACS Omega. 2025 Jan 16;10(3):3182-3189. doi: 10.1021/acsomega.4c10686. eCollection 2025 Jan 28.