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喀麦隆北部塞坎德和加希加地区粘土材料的矿物学、物理化学和陶瓷性能及其在陶器生产中的适用性。

Mineralogical, physico-chemical and ceramic properties of clay materials from Sekandé and Gashiga (North, Cameroon) and their suitability in earthenware production.

作者信息

Kagonbé B P, Tsozué D, Nzeukou A N, Ngos S

机构信息

Department of Earth Sciences, Faculty of Science, University of Maroua, P.O. Box 814 Maroua, Cameroon.

Local Materials Authority Promotion (MIPROMALO), P.O. Box 2396 Yaoundé, Cameroon.

出版信息

Heliyon. 2021 Jul 16;7(7):e07608. doi: 10.1016/j.heliyon.2021.e07608. eCollection 2021 Jul.

Abstract

Clayey materials from Sekandé and Gashiga localities in the northern part in Cameroon traditionally used for pottery were studied. Eight samples were collected and investigated by XRD, IR, XRF, physical and firing properties from 900, 1000 and 1100 °C. In term of mineralogy, studied clays are rich in smectites, illite, kaolinite, quartz, feldspar and mica. Physicochemically, results show large particle size variations with high plasticity (18-30%). Clay fraction (<2 μm) ranges from 18 to 38% and sand fraction from 40 to 53%. Si0 (46-55%) and AlO (19-21%) are major chemicals oxides, followed by FeO (6.68-10.82%) and alcali and alcali-earth elements (8-10%). These characteristics govern their behavior on firing with temperature development. The color of specimens was predominantly red after firing. Between 900 and 1100 °C, their color ranged from reddish brown, red yellow or brown red to red. The linear shrinkage values vary from 0.5% to 7%, weight loss from 4% to 9% and bulk density from 1.74 to 2.21 g/m. These values increased gradually for specimens fired from 900 to 1100 °C. The water absorption decreased from 17% to 14%. The evaluation of the studied clays based on their mineralogical, physicochemical and ceramic properties revealed that they are suitable for the manufacture of earthenware products like fired bricks.

摘要

对喀麦隆北部塞坎德和加希加地区传统上用于制陶的黏土材料进行了研究。采集了八个样本,并通过X射线衍射(XRD)、红外光谱(IR)、X射线荧光光谱(XRF)以及在900℃、1000℃和1100℃下的物理和烧制性能进行了研究。在矿物学方面,所研究的黏土富含蒙脱石、伊利石、高岭石、石英、长石和云母。从物理化学角度来看,结果显示颗粒尺寸变化较大,可塑性高(18 - 30%)。黏土部分(<2μm)占18%至38%,砂部分占40%至53%。二氧化硅(46 - 55%)和氧化铝(19 - 21%)是主要化学氧化物,其次是氧化亚铁(6.68 - 10.82%)以及碱金属和碱土元素(8 - 10%)。这些特性决定了它们在烧制过程中随温度变化的行为。烧制后试样的颜色主要为红色。在900℃至1100℃之间,其颜色从红棕色、红黄或棕红色到红色不等。线性收缩率值在0.5%至7%之间,重量损失在4%至9%之间,堆积密度在1.74至2.21 g/m之间。对于在900℃至1100℃烧制的试样,这些值逐渐增加。吸水率从17%降至14%。基于所研究黏土的矿物学、物理化学和陶瓷性能进行的评估表明,它们适合制造如烧制砖等陶器产品。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4298/8322286/7227c75a9720/gr1.jpg

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