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微量铒添加对铸造Al-Cu-Mg-Ag合金微观组织和力学性能的影响。

Effect of Minor Er Additions on the Microstructures and Mechanical Properties of Cast Al-Cu-Mg-Ag Alloys.

作者信息

Xie Haoyu, Zhao Juangang, Cao Jing, Luo Lei, Guo Shuai, Ou Linnan, Liu Zhiyi, Bai Song

机构信息

School of Material Science and Engineering, Central South University, Changsha 410083, China.

Key Laboratory of Nonferrous Metal Materials Science and Engineering, Central South University, Changsha 410083, China.

出版信息

Materials (Basel). 2021 Jul 28;14(15):4212. doi: 10.3390/ma14154212.

Abstract

The microstructures and mechanical properties of novel cast Al-Cu-Mg-Ag alloys with and without minor additions of Er (0.09 and 0.2 wt %) are investigated by Vickers hardness tests, tensile tests, optical metallographic examination, scanning electron microscopy (SEM), transmission electron microscopy (TEM), and X-ray diffraction (XRD). The results reveal that the Er addition decreases the hardness value of peak-aged Al-Cu-Mg-Ag alloy but has little influence on the time required for achieving the peak aging condition. Meanwhile, the Ω phase is suppressed in Er-added alloys, leading to a lower tensile strength at room temperature, which causes the (Mg, Ag, Er, V, Ti)-rich phase in the matrix in Er-added alloys. This blocky phase consumes available Mg and Ag atoms for Ω nucleation, leading to the low number density of Ω plates. The strength properties of Er-added alloys at 300 °C are found to be enhanced, which benefits from the pinning effect of the AlCuEr phase on grain boundaries. Meanwhile, the brittle fracture of Er-added alloys at room temperature is directly associated with the AlCuEr phase and the blocky (Mg, Ag, Er, V, Ti)-rich phase, which acts as the source of microcracks during deformation. In addition, no obvious grain refinement effect can be observed in Er-added alloys.

摘要

通过维氏硬度测试、拉伸试验、光学金相检验、扫描电子显微镜(SEM)、透射电子显微镜(TEM)和X射线衍射(XRD),研究了添加和未添加微量Er(0.09和0.2 wt%)的新型铸造Al-Cu-Mg-Ag合金的微观结构和力学性能。结果表明,添加Er会降低峰值时效Al-Cu-Mg-Ag合金的硬度值,但对达到峰值时效状态所需的时间影响不大。同时,添加Er的合金中Ω相受到抑制,导致室温下的抗拉强度较低,这使得添加Er的合金基体中出现富(Mg、Ag、Er、V、Ti)相。这种块状相消耗了用于Ω形核的可用Mg和Ag原子,导致Ω板的数量密度较低。发现添加Er的合金在300°C时的强度性能得到增强,这得益于AlCuEr相对晶界的钉扎作用。同时,添加Er的合金在室温下的脆性断裂与AlCuEr相和块状富(Mg、Ag、Er、V、Ti)相直接相关,后者在变形过程中充当微裂纹的源头。此外,在添加Er的合金中未观察到明显的晶粒细化效果。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a520/8348178/98a19833bdd3/materials-14-04212-g001.jpg

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