Neogi Sukanya, Kumar Ghosh Asim, Mandal Saurodeep, Ghosh Debashis, Ghosh Sumit, Hajra Alakananda
Department of Chemistry, Visva-Bharati (A Central University), Santiniketan 731235, India.
Department of Chemistry, St. Joseph's College (Autonomous), Bangalore 560027, India.
Org Lett. 2021 Aug 20;23(16):6510-6514. doi: 10.1021/acs.orglett.1c02322. Epub 2021 Aug 11.
A mild, efficient, and one-pot protocol for three-component carbosilylation of alkenes with imidazoheterocycle and silanes has been developed by merging iron(II) and visible-light photocatalysis. This C-C and C-Si bond-forming method provides functionalized organosilicon derivatives having imidazoheterocycles moieties in good yields. The reaction possibly proceeds through a radical pathway.
通过结合铁（II）和可见光光催化，开发了一种温和、高效的一锅法，用于烯烃与咪唑杂环和硅烷的三组分碳硅基化反应。这种形成碳-碳和碳-硅键的方法能以良好的产率提供具有咪唑杂环部分的功能化有机硅衍生物。该反应可能通过自由基途径进行。
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