Research Institute on Membrane Technology-National Research Council (CNR-ITM), Via Pietro Bucci 17C, Rende CS 87036, Italy.
Graphene Labs, Fondazione Istituto Italiano di Tecnologia, Genova, Via Morego 3016163, Italy.
Water Res. 2021 Sep 15;203:117503. doi: 10.1016/j.watres.2021.117503. Epub 2021 Aug 2.
Water scarcity forces the science to find the most environmentally friendly propulsion technology for supplying plentiful freshwater at low energy costs. Membrane Distillation well meets criteria of eco-friendly management of natural resources, but it is not yet competitive on scale. Herein, we use a dichalchogenide compound (BiTe) as a conceivable source to accelerate the redesign of advanced membranes technologies such as thermally driven membrane distillation. A procedure based on assisted dispersant liquid phase exfoliation is used to fill PVDF membranes. Key insights are gained in the crucial role of this topological material confined in hydrophobic membranes dedicated to recovery of freshwater from synthetic seawater. Intensified water flux together with reduced energy consumption is obtained into one pot, thereby gathering ultrafast production and thermal efficiency in a single device. BiTe-enabled membranes show ability to reduce the resistance to mass transfer while high resistance to heat loss is opposite. Permeate flux is kept stable and salt rejection is higher than 99.99% during 23 h-MD test. Our results confirm the effectiveness of chalcogenides as frontier materials for new-concept water desalination through breakthrough thermally-driven membrane distillation, which is regarded as a new low-energy and sustainable solution to address the growing demand for access to freshwater.
水资源短缺迫使科学界寻找最环保的推进技术,以低成本提供大量淡水。膜蒸馏完全符合自然资源环保管理的标准,但在规模上还没有竞争力。在这里,我们使用一种二卤代物化合物(BiTe)作为加速重新设计先进膜技术(如热驱动膜蒸馏)的一种设想来源。采用基于辅助分散剂液相剥离的方法对 PVDF 膜进行填充。在从合成海水中回收淡水的疏水性膜中,这种拓扑材料的关键作用得到了深入的了解。强化水通量和降低能耗同时得到了提高,从而在单个装置中汇集了超快生产和热效率。BiTe 增强型膜能够降低传质阻力,同时又能提高热损失阻力。在 23 小时 MD 测试中,透过通量保持稳定,盐截留率高于 99.99%。我们的结果证实了硫属化合物作为新概念水淡化的前沿材料的有效性,通过突破性的热驱动膜蒸馏,这被认为是解决对获取淡水的日益增长的需求的一种新的低能耗和可持续的解决方案。