Highly aligned welding of ultrathin graphene layer to robust carbon nanotube film for significantly enhanced thermal conductivity.

Carbon nanotube (CNT) films have demonstrated great potential for highly efficient thermal management materials. However, how to enable a combined feature of excellent thermal conductivity and structural robustness, which is crucial for the high-performance realization, still remains challenging. Herein, an effective and facile strategy to solve the problem was proposed by developing a graphene (G)/CNT film with highly aligned welding of ultrathin G layer to robust CNT film. The unique architectural features of the obtained composite film enabled a high tensile strength (116 MPa) and electric conductivity (1.7 × 10S cm). Importantly, the thermal conductivity was significantly improved compared to neat CNT film, and reached as high as 174 W mK. In addition, the G/CNT film featured a superior electromagnetic shielding performance. This work provides useful guidelines for designing and fabricating the composite CNT film with prominent thermal conductivity, as well as excellent mechanical and electrical properties.