Institut de Chimie de Strasbourg, UMR 7177 CNRS-Université de Strasbourg, 4, rue Blaise Pascal, 67000, Strasbourg, France.
Chemistry. 2021 Nov 22;27(65):16071-16081. doi: 10.1002/chem.202102277. Epub 2021 Oct 8.
Polyoxometalates (POMs) can act as unique reservoirs for multiple electron transfers. As POMs display only weak absorption in the visible spectrum, they can be associated with chromophores such as porphyrins and porphyrin antennae. In this Minireview, the research dedicated to the combination of porphyrins and polyoxometalates is put in context and the state of the art identifying the challenges addressed in the optimization of hybrid materials for applications is detailed.
多金属氧酸盐（POMs）可以作为多种电子转移的独特储库。由于 POMs 在可见光谱中仅显示出微弱的吸收，因此可以将它们与发色团（如卟啉和卟啉天线）结合使用。在这篇综述中，将 POMs 与卟啉结合的研究置于上下文中，并详细介绍了为应用优化杂化材料所解决的挑战的最新进展。
