Synthesis and Characterization of Sn, Ge, and Zr Isomorphous Substituted MFI Nanosheets for Glucose Isomerization to Fructose.

Various metals including Sn, Ge, and Zr have been successfully incorporated into the MFI nanosheets via a one-pot synthesis. The as-synthesized zeolites exhibit high external surface area and mesopore volume without large metal oxides aggregated on zeolite surfaces. Interestingly, the successful introduction of heteroatoms in MFI nanosheets can be confirmed by shifted XRD peaks corresponding to the unit cell expansion due to the replacement of metals into the framework. In addition, the UV-Vis absorbance spectra reveal that at the suitable metal loading the incorporated tetrahedral coordination of metal species in the zeolite framework has been obtained. To illustrate the benefits of the prepared catalysts, the glucose isomerization to fructose was carried out in a water/dioxane system. Obviously, the SnMFI-NS samples, containing the high dispersion of metal isomorphous species demonstrate the outstanding catalytic behavior in term of fructose selectivity (>85 %).