[Preparation of melamine-functionalized porous organic polymer and its adsorption properties for methyl orange].

In this work, a polymer precursor was first synthesized using -terphenyl (TP) and terephthaloyl chloride (TC) as monomers. Then, cross-linking was realized by means of a Schiff base reaction with melamine (MA) as a modifier to obtain an amine-functionalized porous organic polymer TP-TC-MA. The synthesized polymers were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared (FT-IR) spectroscopy, X-ray diffraction (XRD), and point of zero charge (pH) measurements, as well as on the basis of nitrogen adsorption-desorption isotherms. Adsorption experiments were carried out to evaluate the adsorption properties of TP-TC-MA for methyl orange (MO), a typical anionic azo dye that has widespread industrial application. The amount of MO adsorbed on TP-TC-MA was evaluated by ultraviolet-visible (UV-Vis) spectroscopy at a wavelength of 463 nm. Microscopic analysis revealed that the as-synthesized polymer had an aggregated particle-shaped structure. XRD spectra confirmed that TP-TC-MA was an amorphous polymer, consistent with the results of high-resolution TEM experiments. The Brunauer-Emmett-Teller (BET) specific surface area and total pore volume of TP-TC-MA were determined as 708.5 m /g and 0.556 cm/g, respectively. The measured pH of TP-TC-MA was 4.0, probably because of the abundant nitrogen-containing groups provided by MA. The factors affecting adsorption, such as pH, adsorbent dosage, contact time, initial pollutant concentration, and ionic strength, were investigated. Because of the protonation of the N-atom in TP-TC-MA, the pH had a strong impact on the adsorption of MO. The removal efficiency could be maximized at the optimized pH of 3.0. The adsorption equilibrium isotherm, measured at 25 ℃ and a concentration of 50-500 mg/L, showed that the MO adsorption over TP-TC-MA followed the Langmuir isotherm, with a maximum adsorption capacity of 156.3 mg/g. The modeling of the experimental adsorption data was consistent with the pseudo-second-order kinetic model, which indicated fast adsorption and chemisorption as the dominant mechanism. With increasing ionic strength, the adsorption of MO slightly decreased, suggesting a partial antagonistic ion effect. Results of the selectivity study revealed that TP-TC-MA was more selective toward MO than methylene blue (MB), which indicated that electrostatic interactions played a significant role during the adsorption progress. Five adsorption-desorption cycles showed that TP-TC-MA could be regenerated without significant deterioration of its adsorption efficiency, indicating that it has good stability and reusability. The observed adsorption performance indicated that this MA-modified porous organic polymer offers prospects for further research and application in the treatment of dye-containing wastewaters.