Lamellar Assembly Mechanism on Dendritic Ring-Banded Spherulites of Poly(ε-caprolactone).

The self-assembly structures of lamellae in optical ring bands have a critical effect on their optical and physical arrangements. Two different types of dendritic banded spherulites (namely ring-banded and zigzag ring-banded) are formed in poly(ε-caprolactone)/poly (phenyl methacrylate) blend at crystallization temperatures of 42 and 46 °C, respectively. The difference in optical birefringence of ring bands in two types of spherulites is resolved by means of direct morphological comparison. Banded spherulites are fractured carefully to facilitate lamellar orientation analyses of both the top surface and the interior surface. The results have revealed the existence of tree-like dendritic fractal growth lamellar assemblies in both banded spherulites. The optical ring patterns of the banded spherulites are differentiated mainly by the fractal orientation of the edge-on crystal branches in the ridge region. On the basis of detailed morphological analysis, 3D-lamellar assembly mechanisms are proposed to explain the growth of dendritic ring-banded spherulites at 42 °C and dendritic zigzag ring-banded spherulites at 46 °C.