镍配合物在 C‒P 键形成中的作用。

Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, Russia.

Molecules. 2021 Aug 31;26(17):5283. doi: 10.3390/molecules26175283.

This review is a comprehensive account of reactions with the participation of nickel complexes that result in the formation of carbon-phosphorus (C‒P) bonds. The catalytic and non-catalytic reactions with the participation of nickel complexes as the catalysts and the reagents are described. The various classes of starting compounds and the products formed are discussed individually. The several putative mechanisms of the nickel catalysed reactions are also included, thereby providing insights into both the synthetic and the mechanistic aspects of this phosphorus chemistry.

这篇综述全面介绍了镍配合物参与形成碳-磷（C-P）键的反应。描述了镍配合物作为催化剂和试剂参与的催化和非催化反应。单独讨论了各种起始化合物和形成的产物。还包括几种假定的镍催化反应机制，从而深入了解了这一磷化学的合成和机理方面。