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白葡萄酒的光致味变:谷胱甘肽、二氧化硫和可水解单宁的保护作用。

Light-Struck Taste in White Wine: Protective Role of Glutathione, Sulfur Dioxide and Hydrolysable Tannins.

机构信息

Department of Food, Environmental and Nutritional Sciences, Università degli Studi di Milano, Via G. Celoria 2, 20133 Milan, Italy.

出版信息

Molecules. 2021 Aug 31;26(17):5297. doi: 10.3390/molecules26175297.

Abstract

Light exposure of white wine can cause a light-struck taste (LST), a fault induced by riboflavin (RF) and methionine (Met) leading to the formation of volatile sulfur compounds (VSCs), including methanethiol (MeSH) and dimethyl disulfide (DMDS). The study aimed to investigate the impact of different antioxidants, i.e., sulfur dioxide (SO), glutathione (GSH) and chestnut tannins (CT), on preventing LST in model wine (MW) and white wine (WW), both containing RF and Met. Both MW and WW samples were added with the antioxidants, either individually or in different combinations, prior to 2-h light exposure and they were stored in the dark for 24 months. As expected, the light induced the degradation of RF in all the conditions assayed. Met also decreased depending on the antioxidants added. The presence of antioxidants limited the formation of LST as lower concentrations of VSCs were found in both MW and WW samples. In the latter matrix, neither MeSH nor DMDS were detected in the presence of CT, while only DMDS was found in WW+GSH, WW+SO+GSH and WW+CT+SO samples at a concentration lower than the perception thresholds. Considering the antioxidants individually, the order of their effectiveness was CT ≥ GSH > SO in WW under the adopted experimental conditions. The results indicate tannins as an effective enological tool for preventing LST in white wine and their use will be further investigated in different white wines under industrial scale.

摘要

光照会使白葡萄酒产生光致异味(LST),这是由核黄素(RF)和蛋氨酸(Met)引发的缺陷,导致挥发性硫化合物(VSCs)的形成,包括甲硫醇(MeSH)和二甲基二硫醚(DMDS)。本研究旨在研究不同抗氧化剂,即二氧化硫(SO)、谷胱甘肽(GSH)和板栗单宁(CT),对模型酒(MW)和白葡萄酒(WW)中 LST 的预防作用,这两种酒均含有 RF 和 Met。MW 和 WW 样品在光照前添加抗氧化剂,无论是单独添加还是不同组合添加,然后在黑暗中储存 24 个月。正如预期的那样,光照会诱导所有条件下 RF 的降解。根据添加的抗氧化剂的不同,Met 的含量也会下降。抗氧化剂的存在限制了 LST 的形成,因为在 MW 和 WW 样品中发现 VSCs 的浓度较低。在后一种基质中,在 CT 的存在下,既没有检测到 MeSH 也没有检测到 DMDS,而在 WW+GSH、WW+SO+GSH 和 WW+CT+SO 样品中,仅在 DMDS 的浓度低于感知阈值时检测到。考虑到抗氧化剂的个体,在采用的实验条件下,在 WW 中,它们的有效性顺序为 CT≥GSH>SO。结果表明,单宁是预防白葡萄酒光致异味的有效酿造工具,将在不同的白葡萄酒中进一步在工业规模下进行研究。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bcd8/8434244/847e450c1ec2/molecules-26-05297-g0A1.jpg

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