Residues and Resource Reclamation Centre, Nanyang Environment and Water Research Institute, Nanyang Technological University, 1 Cleantech Loop, CleanTech One, Singapore 637141, Singapore; Faculty of Science and Engineering, Åbo Akademi University, 20500 Turku, Finland.
Residues and Resource Reclamation Centre, Nanyang Environment and Water Research Institute, Nanyang Technological University, 1 Cleantech Loop, CleanTech One, Singapore 637141, Singapore.
J Hazard Mater. 2022 Feb 5;423(Pt A):127057. doi: 10.1016/j.jhazmat.2021.127057. Epub 2021 Aug 30.
During high temperature slagging gasification of municipal solid waste (MSW), coal coke is typically used as an auxiliary fuel to maintain the high temperature in the gasifier and convert ashes into slag. Herein, biomass charcoal was utilized as a greener and more sustainable auxiliary fuel to replace the coal coke during stable and continuous gasification of MSW. Several monitoring characteristics were assessed, like operating conditions of the gasifier, influence of local MSW properties generated in Singapore, environmental impacts, and main by-products (slag, fly ash and metals). The performance data revealed that the replacement of coal coke with biomass charcoal provided significant environmental benefits. The use of biomass charcoal resulted in 78% less SO emissions, and 22% less generated fly ash because the lower sulfur content in biomass charcoal resulted in a 32% reduced use of sorbent for flue gas treatment. Furthermore, there was clear evidence of a 22% carbon footprint reduction due to replacing fossil fuel as auxiliary fuel. In addition, the slag characteristics demonstrated lower heavy metals leaching as compared to the incineration bottom ash generated from the conventional MSW incineration plant suggesting its great potential in the application as clean and green waste-derived material in the construction industry.
在城市固体废物(MSW)的高温熔融气化过程中,通常使用煤焦作为辅助燃料,以维持气化炉内的高温并将灰分转化为炉渣。在此,利用生物质炭作为一种更环保、更可持续的辅助燃料,在 MSW 的稳定连续气化过程中替代煤焦。评估了一些监测特性,如气化炉的运行条件、新加坡当地产生的 MSW 特性的影响、环境影响以及主要副产物(炉渣、飞灰和金属)。性能数据表明,用生物质炭替代煤焦带来了显著的环境效益。由于生物质炭的硫含量较低,用于烟气处理的吸附剂减少了 32%,因此使用生物质炭替代煤焦可将 SO 排放量减少 78%,飞灰生成量减少 22%。此外,由于将化石燃料替代为辅助燃料,碳足迹减少了 22%,这是显而易见的。此外,与传统 MSW 焚烧厂产生的焚烧底灰相比,炉渣特性表明重金属浸出率较低,这表明其在建筑行业中作为清洁绿色废物衍生材料的应用具有巨大潜力。