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[通过放射学方法获得的用于生物医学目的的聚合物材料。II. 丙烯酰胺和N-乙烯基吡咯烷酮的辐射聚合]

[Polymer materials for biomedical purposes obtained by radiological methods. II. Radiation polymerization of acrylamides and N-vinylpyrrolidone].

作者信息

Rosiak J, Burczak K, Olejniczak J, Pekala W

机构信息

Miedzyresortowy Instytut Techniki Radiacyjnej Politechniki Lódzkiej.

出版信息

Polim Med. 1987;17(3-4):99-116.

PMID:3452819
Abstract

The radiation polymerization of acrylamide and N-vinylpyrrolidin-2-one in aqueous solutions has been investigated. The effect of the monomer concentration as well as the dose rate of the ionizing radiation on the process has been determined. The radical mechanism of the polymerization process has been confirmed experimentally. The effect of the individual transient species of the water radiolysis on the initiation of the polymerization process as well as the changes of the molecular weights of the arising polymers have been investigated. The dependence of the galation dose of the system on the monomer concentration has been determined.

摘要

对丙烯酰胺和N-乙烯基吡咯烷-2-酮在水溶液中的辐射聚合进行了研究。确定了单体浓度以及电离辐射剂量率对该过程的影响。通过实验证实了聚合过程的自由基机理。研究了水辐射分解的各个瞬态物种对聚合过程引发的影响以及所生成聚合物分子量的变化。确定了该体系凝胶剂量对单体浓度的依赖性。

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