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对映选择性杀菌活性和手性农药三氯苯唑对早期小麦生长的毒性。

Enantioselective Fungicidal Activity and Toxicity to Early Wheat Growth of the Chiral Pesticide Triticonazole.

机构信息

Beijing Advanced Innovation Center for Food Nutrition and Human Health, Department of Applied Chemistry, China Agricultural University, No. 2 West Yuanmingyuan Road, Beijing 100193, P.R. China.

Institute for the Control of Agrochemicals, Ministry of Agriculture and Rural Affairs (ICAMA), No. 22 Maizidian Street, Chaoyang, Beijing 100125, P.R. China.

出版信息

J Agric Food Chem. 2021 Sep 29;69(38):11154-11162. doi: 10.1021/acs.jafc.0c07210. Epub 2021 Sep 16.

Abstract

In this study, the enantioselective activity of the chiral fungicide triticonazole (TRZ) against target pathogens of seed-borne diseases and the effect on the early phenotypic indexes and physiological and biochemical indexes of wheat following the soaking of seeds were studied. -TRZ had low fungicidal activity and significantly inhibited the germination of wheat seeds. Seedlings in the -TRZ treatment group suffered severe oxidative damage; the contents of glutathione (GSH) and malondialdehyde (MDA) were significantly increased. -TRZ significantly inhibited the synthesis of gibberellin (GA) and ethylene (ETH), while it significantly increased that of jasmonic acid (JA). -TRZ showed the highest activity against two smut fungi; the treatment of seeds with 5 g (ai)/100 kg -TRZ had little influence on early wheat growth. The plant hormones were synthesized normally; seedlings grew well, and the fresh weight increased significantly following this treatment. Based on these data, we propose to develop and apply -TRZ using the national recommended doses to control seed-borne diseases of wheat.

摘要

在这项研究中,研究了手性杀菌剂三唑酮(TRZ)对种子带菌病害的目标病原体的对映选择性活性,以及种子浸泡后对小麦早期表型指标和生理生化指标的影响。-TRZ 的杀菌活性低,对小麦种子的萌发有明显抑制作用。-TRZ 处理组的幼苗遭受严重的氧化损伤;谷胱甘肽(GSH)和丙二醛(MDA)的含量明显增加。-TRZ 显著抑制赤霉素(GA)和乙烯(ETH)的合成,而显著增加茉莉酸(JA)的合成。-TRZ 对两种黑粉病真菌表现出最高的活性;用 5 g(ai)/100 kg -TRZ 处理种子对小麦早期生长影响很小。植物激素正常合成;幼苗生长良好,经此处理后鲜重显著增加。基于这些数据,我们建议使用国家推荐剂量开发和应用 -TRZ 来控制小麦的种子带菌病害。

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