Ernst Ruska-Centre for Microscopy and Spectroscopy with Electrons, Peter Grünberg Institute, Forschungszentrum Jülich GmbH, 52425 Jülich, Germany.
Department of Chemical Engineering, Northeastern University, Boston, Massachusetts 02115, United States.
Nano Lett. 2021 Oct 13;21(19):8135-8142. doi: 10.1021/acs.nanolett.1c02573. Epub 2021 Sep 16.
Iron and its alloys have made modern civilization possible, with metallic meteorites providing one of the human's earliest sources of usable iron as well as providing a window into our solar system's billion-year history. Here highest-resolution tools reveal the existence of a previously hidden FeNi nanophase within the extremely slowly cooled metallic meteorite NWA 6259. This new nanophase exists alongside Ni-poor and Ni-rich nanoprecipitates within a matrix of tetrataenite, the uniaxial, chemically ordered form of FeNi. The ferromagnetic nature of the nanoprecipitates combined with the antiferromagnetic character of the FeNi nanophases gives rise to a complex magnetic state that evolves dramatically with temperature. These observations extend and possibly alter our understanding of celestial metallurgy, provide new knowledge concerning the archetypal Fe-Ni phase diagram and supply new information for the development of new types of sustainable, technologically critical high-energy magnets.
铁及其合金使现代文明成为可能,金属陨石不仅为人类提供了最早的可用铁源,还为我们了解太阳系数十亿年的历史提供了窗口。在这里,最高分辨率的工具揭示了在极其缓慢冷却的金属陨石 NWA 6259 中存在以前隐藏的 FeNi 纳米相。这种新的纳米相与 Ni 贫和 Ni 富纳米沉淀物一起存在于 tetrataenite 基体中,FeNi 的单轴、化学有序形式。纳米沉淀物的铁磁性与 FeNi 纳米相的反铁磁性相结合,导致复杂的磁状态随温度急剧变化。这些观察结果扩展并可能改变了我们对天体冶金学的理解,提供了有关典型 Fe-Ni 相图的新知识,并为开发新型可持续、技术关键的高能磁铁提供了新信息。