Department of Science, Institute for Information Technologies Kragujevac, University of Kragujevac, Jovana Cvijića bb, 34000 Kragujevac, Serbia.
Curr Org Synth. 2022;19(3):293-316. doi: 10.2174/1570179418666210917152537.
Selenium promoted-cyclization of unsaturated substrates containing internal nitrogen nucleophiles, such as different amines and amides, including the examples of its application in the synthesis of more complex polycyclic compounds is reviewed. Selenocyclization reactions of some more specific polyfunctional substrates, like Biginelli hybrids and hydantoins, are also covered.
综述了硒促进含内部氮亲核试剂(如各种胺和酰胺)的不饱和底物的环化反应,包括其在合成更复杂的多环化合物中的应用实例。本文还介绍了一些更具特异性的多官能团底物(如比格利希杂环和海因衍生物)的硒环化反应。