Improving the single-molecule magnet properties of two pentagonal bipyramidal Dy compounds by the introduction of both electron-withdrawing and -donating groups.

Two mononuclear Dy compounds [Dy(bmbpen-F)X] (X = Cl, 1; Br, 2) with a pentagonal bipyramidal (PBP) geometry were obtained from ,'-bis-(5-methyl-2-hydroxybenzyl)-,'-bis(5-fluoro-2-methylpyridyl)ethylenediamine (Hbmbpen-F) and dysprosium halides. The magnetic anisotropy and single-molecule magnet (SMM) behavior of these PBP compounds were regulated by introducing both electron-withdrawing F atoms into the equatorial pyridine rings and electron-donating -CH groups into the axial phenolic hydroxyl rings. The results of magnetic characterization show that 1 and 2 exhibit single molecule magnet behavior with magnetization reversal barriers of 990(13) and 1189(16) K under a zero dc external field and magnetic hysteresis loops up to 26 K and 36 K, respectively. The results of calculations are consistent with the experimental observations, confirming that the simultaneous introduction of electron-withdrawing groups into the equatorial positions and electron-donating groups into the axial positions can lead to PBP Dy-SMMs with improved properties.