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限制在内角为[具体角度]的楔形区域内的聚合物的构型统计

The Configurational Statistics of a Polymer Confined to a Wedge of Interior Angle .

作者信息

Lauritzen J I, DiMarzio E A

机构信息

National Measurement Laboratory, National Bureau of Standards, Washington, D.C. 20234.

出版信息

J Res Natl Bur Stand (1977). 1978 Jul-Aug;83(4):381-385. doi: 10.6028/jres.083.025.

Abstract

The probability distribution for the end-to-end length of a polymer of segments confined in a wedge of interior angle is obtained (2 ≥· > 0). The result is used to evaluate the partition function, , for the cases: (1) one end free - one end tied to the vertex, is proportional to both ends tied to each other at the vertex, , is proportional to .

摘要

得到了内角为(\theta)((2\pi\geq\theta>0))的楔形区域内由(n)个链段组成的聚合物的端到端长度的概率分布。该结果用于评估以下两种情况下的配分函数(Z):(1)一端自由,一端固定在顶点,(Z)与(n^{3/2})成正比;(2)两端在顶点处相互连接,(Z)与(n)成正比。

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