Yang Siyan, Li Wanbo, Song Yajie, Ying Yushan, Wen Rongfu, Du Bingang, Jin Yuankai, Wang Zuankai, Ma Xuehu
State Key Laboratory of Fine Chemicals, Institute of Chemical Engineering, Liaoning Key Laboratory of Clean Utilization of Chemical Resources, Dalian University of Technology, Dalian 116024, China.
Department of Mechanical Engineering, City University of Hong Kong, Kowloon, Hong Kong 999077, China.
Langmuir. 2021 Oct 12;37(40):11931-11938. doi: 10.1021/acs.langmuir.1c02159. Epub 2021 Sep 27.
Frost accretion occurs ubiquitously in various industrial applications and causes tremendous energy and economic loss, as manifested by the Texas power crisis that impacted millions of people over a vast area in 2021. To date, extensive efforts have been made on frost removal by micro-engineering surfaces with superhydrophobicity or lubricity. On such surfaces, air or oil cushions are introduced to suspend the frost layer and promote the rapid frost sliding off, which, although promising, faces the instability of the cushions under extreme frosting conditions. Most existing hydrophilic surfaces, characterized by large interfacial adhesion, have long been deemed unfavorable for frost shedding. Here, we demonstrated that a hydrophilic and slippery surface can achieve efficient defrosting. On such a surface, the hydrophilicity gave rise to a highly interconnected basal frost layer that boosted the substrate-to-frost heat transfer; then, the resulting melted frost readily slid off the surface due to the superb slipperiness. Notably, on our surface, the retained meltwater coverage after frost sliding off was only 2%. In comparison to two control surfaces, for example, surfaces lacking either hydrophilicity or slipperiness, the defrosting efficiency was 13 and 19 times higher and the energy consumption was 2.3 and 6.2 times lower, respectively. Our study highlights the use of a hydrophilic surface for the pronounced defrosting in a broad range of industrial applications.
结霜现象在各种工业应用中普遍存在,并造成了巨大的能源和经济损失,2021年影响大面积数百万人口的得克萨斯州电力危机就是明证。迄今为止,人们已经通过具有超疏水性或润滑性的微工程表面在除霜方面做出了广泛努力。在这样的表面上,引入空气或油垫以悬浮霜层并促进霜快速滑落,尽管前景广阔,但在极端结霜条件下垫体存在不稳定性问题。大多数现有的亲水性表面,其特点是界面附着力大,长期以来一直被认为不利于霜的脱落。在此,我们证明了亲水性和光滑性兼具的表面能够实现高效除霜。在这样的表面上,亲水性产生了高度相互连接的底部霜层,增强了从基底到霜的热传递;然后,由于其卓越的光滑性,融化的霜很容易从表面滑落。值得注意的是,在我们的表面上,霜滑落之后残留的融水覆盖率仅为2%。例如,与两个对照表面(即缺乏亲水性或缺乏光滑性的表面)相比,除霜效率分别高出13倍和19倍,能耗分别降低2.3倍和6.2倍。我们的研究突出了亲水性表面在广泛工业应用中显著除霜的用途。