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再生聚乙烯渔网面临的挑战与机遇:迈向循环经济

Challenges and Opportunities for Recycled Polyethylene Fishing Nets: Towards a Circular Economy.

作者信息

Juan Rafael, Domínguez Carlos, Robledo Nuria, Paredes Beatriz, Galera Sara, García-Muñoz Rafael A

机构信息

LATEP, Polymer Technology Laboratory, Rey Juan Carlos University, Tulipán St., Móstoles, 28933 Madrid, Spain.

GIQA, Group of Environmental and Chemical Engineering, ESCET, Rey Juan Carlos University, Tulipán St., Móstoles, 28933 Madrid, Spain.

出版信息

Polymers (Basel). 2021 Sep 17;13(18):3155. doi: 10.3390/polym13183155.

Abstract

Plastic waste generation has become an important problem that critically affects marine and oceans environments. Fishing nets gear usually have a relatively short lifespan, and are abandoned, discarded and lost, what makes them one of the largest generators of ocean plastic waste. Recycled polyolefin resins from fishing nets (rFN), especially from polyethylene (PE), have poor properties due to the presence of contaminants and/or excessive degradation after its lifetime. These reasons limit the use of these recycled resins. This work aims to study the incorporation of recycled fishing nets PE-made to different grades of virgin PE, in order to evaluate the potential use of these rFN in the development of new products. The recovered fishing nets have been fully characterized to evaluate its properties after the collection and recycling process. Then, different PE virgin resins have been mechanically blended with the recovered fishing nets at different recycling contents to study its feasibility for fishing nets or packaging applications. Critical mechanical properties for these applications, as the elongation at break, impact strength or environmental stress cracking resistance have been deeply evaluated. Results show important limitations for the manufacture of fibers from recycled PE fishing nets due to the presence of inorganic particles from the marine environment, which restricts the use of rFN for its original application. However, it is proved that a proper selection of PE raw resins, to be used in the blending process, allows other possible applications, such as non-food contact bottles, which open up new ways for using the fishing nets recyclates, in line with the objectives pursued by the Circular Economy of Plastics.

摘要

塑料垃圾的产生已成为一个严重影响海洋环境的重要问题。渔网渔具通常使用寿命相对较短,会被遗弃、丢弃或遗失,这使其成为海洋塑料垃圾的最大来源之一。来自渔网(rFN),特别是聚乙烯(PE)材质的渔网的回收聚烯烃树脂,由于存在污染物和/或使用期后的过度降解,性能较差。这些原因限制了这些回收树脂的使用。这项工作旨在研究将回收的PE材质渔网掺入不同等级的原生PE中,以评估这些rFN在新产品开发中的潜在用途。对回收的渔网进行了全面表征,以评估其在收集和回收过程后的性能。然后,将不同的原生PE树脂与回收的渔网在不同的回收含量下进行机械共混,以研究其用于渔网或包装应用的可行性。对这些应用至关重要的机械性能,如断裂伸长率、冲击强度或耐环境应力开裂性,已进行了深入评估。结果表明,由于海洋环境中存在无机颗粒,用回收的PE渔网制造纤维存在重大限制,这限制了rFN用于其原始应用。然而,事实证明,在共混过程中适当选择PE原料树脂,可以实现其他可能的应用,如非食品接触瓶,这为渔网回收物的利用开辟了新途径,符合塑料循环经济的目标。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e3af/8470735/7dc08a969c59/polymers-13-03155-g001.jpg

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