分担负荷:应力重新分布决定聚合物双网络的断裂
Sharing the Load: Stress Redistribution Governs Fracture of Polymer Double Networks.
作者信息
Tauber Justin, Rovigatti Lorenzo, Dussi Simone, van der Gucht Jasper
机构信息
Physical Chemistry and Soft Matter, Wageningen University and Research, Stippeneng 4, 6708 WE Wageningen, The Netherlands.
Dipartimento di Fisica, Sapienza-Università di Roma, Piazzale A. Moro 2, 00185 Roma, Italy.
出版信息
Macromolecules. 2021 Sep 28;54(18):8563-8574. doi: 10.1021/acs.macromol.1c01275. Epub 2021 Sep 16.
The stress response of polymer double networks depends not only on the properties of the constituent networks but also on the interactions arising between them. Here, we demonstrate, via coarse-grained simulations, that both their global stress response and their microscopic fracture mechanics are governed by load sharing through these internetwork interactions. By comparing our results with affine predictions, where stress redistribution is by definition homogeneous, we show that stress redistribution is highly inhomogeneous. In particular, the affine prediction overestimates the fraction of broken chains by almost an order of magnitude. Furthermore, homogeneous stress distribution predicts a single fracture process, while in our simulations, fracture of sacrificial chains takes place in two steps governed by load sharing within a network and between networks, respectively. Our results thus provide a detailed microscopic picture of how inhomogeneous stress redistribution after rupture of chains governs the fracture of polymer double networks.
聚合物双网络的应力响应不仅取决于组成网络的性质,还取决于它们之间产生的相互作用。在这里,我们通过粗粒化模拟证明,它们的整体应力响应和微观断裂力学都由这些网络间相互作用的载荷分担所控制。通过将我们的结果与仿射预测进行比较(根据定义,仿射预测中的应力重新分布是均匀的),我们表明应力重新分布是高度不均匀的。特别是,仿射预测高估了断裂链的比例,几乎高出一个数量级。此外,均匀应力分布预测了单一的断裂过程,而在我们的模拟中,牺牲链的断裂分两步进行,分别由网络内部和网络之间的载荷分担控制。因此,我们的结果提供了一个详细的微观图景,说明链断裂后不均匀的应力重新分布如何控制聚合物双网络的断裂。
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