Xia Jinsong, Mahandra Harshit, Ghahreman Ahmad
Hydrometallurgy and Environment Laboratory, Robert M. Buchan Department of Mining, Queen's University, 25 Union Street, Kingston, Ontario K7L 3N6, Canada.
ACS Appl Mater Interfaces. 2021 Oct 13;13(40):47642-47649. doi: 10.1021/acsami.1c13920. Epub 2021 Oct 4.
Activated carbon has been used for gold recovery in the gold mining industry commercially for decades. The high specific surface area and porosity, good affinity to aurocyanide ions, and abundant resources make activated carbon an efficient and economical material for the adsorption of aurocyanide. However, the separation of activated carbon from the slurry is usually a challenge, and the adsorption rate of activated carbon is limited by the coarse particle size. Herein, a simple and sustainable way to recover gold from cyanide solution using magnetic activated carbon synthesized via a solvothermal method has been developed. The synthesized magnetic activated carbon possesses good magnetism (44.57 emu/g) and specific surface area equal to 249.7 m/g. The magnetic activated carbon showed 99.1% recovery efficiency of gold from 10 mg/L solution within 5 h, which is much faster compared to the commercial granular activated carbon, and the magnetic activated carbon can be easily separated from the solution with an external magnet. The adsorption ability of this magnetic activated carbon has been tested under different conditions in the cyanide solution, the adsorption isotherm and kinetics are also investigated. The magnetic activated carbon was also recycled in the adsorption-desorption tests and showed good reusability.
几十年来,活性炭在黄金采矿业中一直被商业用于回收黄金。高比表面积和孔隙率、对金氰化物离子的良好亲和力以及丰富的资源,使活性炭成为吸附金氰化物的高效且经济的材料。然而,从矿浆中分离活性炭通常是一项挑战,并且活性炭的吸附速率受到粗粒度的限制。在此,已开发出一种使用通过溶剂热法合成的磁性活性炭从氰化物溶液中回收金的简单且可持续的方法。合成的磁性活性炭具有良好的磁性(44.57 emu/g),比表面积为249.7 m/g。磁性活性炭在5小时内从10 mg/L的溶液中显示出99.1%的金回收效率,这比商业颗粒活性炭快得多,并且磁性活性炭可以通过外部磁铁轻松地从溶液中分离出来。已在氰化物溶液中的不同条件下测试了这种磁性活性炭的吸附能力,还研究了吸附等温线和动力学。磁性活性炭在吸附-解吸试验中也进行了循环使用,并显示出良好的可重复使用性。