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由木纤维通过自黏合技术制备的生物基复合材料。

Bio-based composites fabricated from wood fibers through self-bonding technology.

机构信息

Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, International Innovation Center for Forest Chemicals and Materials, College of Materials Science and Engineering, Nanjing Forestry University, Nanjing, Jiangsu, 210037, China.

Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, International Innovation Center for Forest Chemicals and Materials, College of Materials Science and Engineering, Nanjing Forestry University, Nanjing, Jiangsu, 210037, China; Aerospace Kaitian Environmental Technology Co., Ltd, Changsha, 410000, China.

出版信息

Chemosphere. 2022 Jan;287(Pt 4):132436. doi: 10.1016/j.chemosphere.2021.132436. Epub 2021 Oct 2.

Abstract

Green composite processing technology of wood fibers is an inevitable choice for global sustainable development. In this research, waste poplar powder with different particle sizes was used to prepare glue-free biocomposites with good mechanical and waterproof properties by hot-molding. The biocomposites made of larger size wood powder had better tensile strength (40.3 MPa) and the biocomposites made of smaller size wood powder had the greater bending strength (50.5 MPa). The thickness swelling rate of the biocomposites was only 4.26% after soaking in water for 24 h. The cross-section morphology of the biocomposites showed that the cell wall collapses enhanced the interfacial bonding. Chemical analysis showed that lignin repolymerized with cellulose and hemicellulose for the vitrification transition. In addition, the biocomposites with excellent mechanical properties had no formaldehyde release, which can replace the traditional density boards made of adhesives and applied as furniture materials and in line with the concept of cleaner production.

摘要

木纤维绿色复合材料加工技术是全球可持续发展的必然选择。本研究采用不同粒径的废弃杨木粉,通过热压模塑制备出具有良好力学性能和防水性能的无胶生物质复合材料。较大粒径木粉制备的复合材料具有较高的拉伸强度(40.3 MPa),较小粒径木粉制备的复合材料具有较大的弯曲强度(50.5 MPa)。复合材料在水中浸泡 24 h 后的厚度膨胀率仅为 4.26%。复合材料的横截面形貌表明,细胞壁的坍塌增强了界面结合。化学分析表明,木质素与纤维素和半纤维素发生重排,发生了玻璃化转变。此外,具有优异力学性能的复合材料无甲醛释放,可替代传统的含胶密度板,用作家具材料,符合清洁生产的理念。

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