Department of Chemical and Materials Engineering, University of Alberta, Edmonton, AB, Canada.
Institut Jean Lamour, Université de Lorraine, CNRS, IJL, Labex DAMAS, F-54000 Nancy, France.
J Colloid Interface Sci. 2022 Feb 15;608(Pt 1):355-365. doi: 10.1016/j.jcis.2021.08.208. Epub 2021 Sep 3.
Aggregate structure is conditioned by a balance of cohesive forces between primary particles and hydrodynamic forces induced by the surrounding flow. Numerical simulations for different ratios between radial and tangential components of cohesive forces to hydrodynamic forces should highlight the role of the each force in aggregate restructuring under shear flow.
Aggregates sharing similar morphological characteristics were algorithmically created. The forces between primary particles were accounted for using models taken from the literature. Aggregates with different cohesive forces were then submitted to shear by imposing a shear stress in the liquid phase. Hydrodynamic forces were calculated following two approaches: first, with a free draining approximation to extract general trends, then with immersed boundaries in a lattice Boltzmann flow solver to fully resolve the flow and particle dynamics.
Aggregate structural changes were tracked over time and their stable final size, or eventual breakage, was recorded. Their final structure was found to depend little on normal cohesive forces but is strongly impacted by tangential forces. Normal forces, however, strongly affect breakage probability. Furthermore, resistance to deformation at the aggregate scale induces a flow disturbance that reduces drag forces compared to the free-draining approximation, significantly impacting aggregate restructuring.
团聚体的结构取决于团聚体内部颗粒之间的黏附力和周围流场产生的流体动力之间的平衡。针对黏附力和流体动力的径向分量与切向分量的不同比值进行数值模拟,应该可以突出每种力在剪切流作用下对团聚体重构的作用。
通过算法创建具有相似形态特征的团聚体。使用文献中的模型来计算团聚体内部颗粒之间的相互作用力。然后通过在液相中施加剪切应力,使具有不同黏附力的团聚体受到剪切。采用两种方法计算流体动力:首先,采用自由排水近似值来提取一般趋势,然后采用格子玻尔兹曼流动求解器中的浸入边界来完全解析流动和颗粒动力学。
随着时间的推移,跟踪团聚体的结构变化,并记录其稳定的最终尺寸或最终的破裂情况。研究发现,团聚体的最终结构几乎不受法向黏附力的影响,但受切向力的影响很大。然而,法向力会强烈影响破裂的概率。此外,在团聚体尺度上抵抗变形会引起流动干扰,与自由排水近似相比,会降低阻力,这会显著影响团聚体的重构。