由钯丝催化的电化学析氢反应。
Electrochemical hydrogen formation catalysed by a Pd string.
作者信息
Tanase Tomoaki, Nakamae Kanako, Miyano Haruka, Fujisawa Yoshimi, Ura Yasuyuki, Nakajima Takayuki
机构信息
Department of Chemistry, Faculty of Science, Nara Women's University, Kitauoya-nishi-machi, Nara 630-8506, Japan.
出版信息
Chem Commun (Camb). 2021 Oct 26;57(85):11264-11267. doi: 10.1039/d1cc04788d.
PMID:34635898
Abstract
The linear Pd complex supported by tetraphosphines reacted with HBF to give an unprecedented linear tetrapalladium complex with a terminal hydride, which promoted electrocatalytic hydrogen formation from HBF in acetonitrile. The 1D coordination polymer of Pd chain confined within Nafion film was applied to the electrocatalytic H formation.
摘要
由四膦支持的线性钯配合物与HBF反应，生成了一种前所未有的带有末端氢化物的线性四钯配合物，该配合物促进了乙腈中HBF的电催化析氢反应。将限制在Nafion膜内的钯链一维配位聚合物应用于电催化析氢反应。
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