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真实暴露等级XC4地中海气候环境对使用含有矿渣、粉煤灰和石灰石的三元胶凝材料制成的砂浆性能的影响。

Effects of a Real Exposure Class XC4 Mediterranean Climate Environment in the Behavior of Mortars Made Using Ternary Binders with Addition of Slag, Fly Ash and Limestone.

作者信息

Ibáñez-Gosálvez Javier, Real-Herraiz Teresa, Ortega José Marcos

机构信息

Departamento de Ingeniería Civil, Universidad de Alicante, Ap. Correos 99, 03080 Alicante, Spain.

Instituto de Matemática Multidisciplinar, Universidad Politécnica de Valencia, Camino de Vera s/n, 46022 Valencia, Spain.

出版信息

Materials (Basel). 2021 Oct 6;14(19):5848. doi: 10.3390/ma14195848.

Abstract

For improving the contribution of the cement industry to mitigate global warming, many strategies have been put into practice, such as the use of eco-friendly cements with the incorporation of additions substituting clinker. Nevertheless, the use of ternary binders for the production of commercial cements is still reduced, particularly in Spain. The purpose of this research is to characterize the long-term influence produced by the exposure to a real in situ inland Mediterranean climate condition in the pore network, parameters related to durability and mechanical performance of mortars made with ternary binders, which incorporated limestone, fly ash, and ground granulated blast-furnace slag, in comparison with mortars without additions and binary blended mortars. The site verified the specifications of exposure class XC4 of Eurocode 2. The ternary and binary binders accomplished the prescriptions of cement type CEM II/B. The pore network was studied with mercury intrusion porosimetry and electrical resistivity. Water absorption, diffusion coefficient, carbonation depth, ultrasonic pulse velocity, compressive and flexural strengths have been determined. The exposure to the environment produced after 250 days an increase in porosity, a loss of pore refinement, a rise of the carbonation depths, and a reduction in the mechanical strengths, highlighting the better overall performance of ternary mortar with both fly ash and slag.

摘要

为提高水泥行业对缓解全球变暖的贡献,已实施了许多策略,例如使用环保水泥并掺入替代熟料的添加剂。然而,三元胶凝材料用于生产商业水泥的情况仍然较少,尤其是在西班牙。本研究的目的是表征在真实的内陆地中海气候条件下,三元胶凝材料(其中包含石灰石、粉煤灰和磨细粒化高炉矿渣)制成的砂浆,与无添加剂砂浆和二元混合砂浆相比,其在孔隙网络、耐久性相关参数和力学性能方面所受到的长期影响。该场地符合欧洲规范2中暴露等级XC4的规定。三元和二元胶凝材料符合水泥类型CEM II/B的规定。通过压汞法和电阻率研究孔隙网络。测定了吸水率、扩散系数、碳化深度、超声脉冲速度、抗压强度和抗折强度。暴露于环境250天后,孔隙率增加、孔隙细化丧失、碳化深度增加以及力学强度降低,突出了同时含有粉煤灰和矿渣的三元砂浆的更好整体性能。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6800/8510225/a96fb5961042/materials-14-05848-g001.jpg

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