Geographical origin determination of Red Huajiao in China using the electronic nose combined with ensemble recognition algorithm.

Red Huajiao was the most important Zanthoxylum species in China, and its quality was highly determined the geographical region. This study was aimed to establish a determination method for the geographical origin recognition of Red Huajiao by using the electronic nose and ensemble recognition algorithm. Six origins of samples were detected by the electronic nose, and two categories of electronic nose sensors characteristic values, named as "optimized characteristic value" and "filtered characteristic value," were obtained by the principal component analysis and discrimination index method and Filter-Wrapper method. Based on the two categories of characteristic values, 22 kinds of model analysis methods, which belonged to five categories of ensemble recognition algorithms were used to recognize the geographical origin. The total recognition accuracy rate of the two categories of characteristic values were 83.9% and 85.7%, respectively. Furthermore, during 22 kinds of model analysis method, the ensemble Subspace KNN and Bagged Trees methods in Ensemble Learning algorithm exhibited the best distinguishing ability with the accuracy rate more than 90%. Therefore, the electronic nose combined with Ensemble Learning would be promising for the geographical origin determination application. PRACTICAL APPLICATION: This work demonstrates that the Red Huajiao can be simply and rapidly determined by using electronic nose combined with ensemble recognition algorithm, allowing to effectively distinguish geographical origin of Red Huajiao, which can provide an important reference for the quality assessment of Huajiao.