Baltatu Madalina Simona, Vizureanu Petrica, Sandu Andrei Victor, Florido-Suarez Nestor, Saceleanu Mircea Vicentiu, Mirza-Rosca Julia Claudia
Department of Technologies and Equipments for Materials Processing, Faculty of Materials Science and Engineering, Gheorghe Asachi Technical University of Iaşi, Blvd. Mangeron, No. 51, 700050 Iasi, Romania.
Romanian Inventors Forum, Iasi. Sf. P. Movila 3, 700089 Iasi, Romania.
Materials (Basel). 2021 Oct 9;14(20):5934. doi: 10.3390/ma14205934.
Titanium alloys are used in medical devices due to their mechanical properties, but also for their corrosion resistance. The natural passivation of titanium-based biomaterials, on the surface of which a dense and coherent film of nanometric thickness is formed, composed mainly of TiO, determines an apparent bioactivity of them. In this paper, the method of obtaining new Ti20MoxSi alloys (x = 0.0, 0.5, 0.75, and 1.0) is presented, their microstructure is analyzed, and their electrochemical responses in Ringer´s solution were systematically investigated by linear polarization, cyclic potential dynamic polarization, and electrochemical impedance spectroscopy (EIS). The alloys corrosion resistance is high, and no evidence of localized breakdown of the passive layer was observed. There is no regularity determined by the composition of the alloys, in terms of corrosion resistance, but it seems that the most resistant is Ti20Mo1.0Si.
钛合金因其机械性能以及耐腐蚀性而被用于医疗设备。钛基金属生物材料的自然钝化作用会在其表面形成一层致密且连贯的纳米级薄膜,主要由TiO组成,这决定了它们具有一定的生物活性。本文介绍了新型Ti20MoxSi合金(x = 0.0、0.5、0.75和1.0)的制备方法,分析了它们的微观结构,并通过线性极化、循环电位动态极化和电化学阻抗谱(EIS)系统地研究了它们在林格氏溶液中的电化学响应。这些合金具有较高的耐腐蚀性,未观察到钝化层局部击穿的迹象。就耐腐蚀性而言,合金成分并未决定出规律,但似乎最耐腐蚀的是Ti20Mo1.0Si。