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基于聚二甲基硅氧烷包覆的SiO纳米颗粒一步制备功能集成器件用于高效连续吸油

One-Step Fabrication of a Functionally Integrated Device Based on Polydimethylsiloxane-Coated SiO NPs for Efficient and Continuous Oil Absorption.

作者信息

Ju Guannan, Zhou Lei, Jiao Chang, Shen Jiafeng, Luan Yihao, Zhao Xinyu

机构信息

School of Materials Science and Engineering, Shandong University of Technology, Zibo 255000, China.

China National Accreditation Service for Conformity Assessment, Beijing 100062, China.

出版信息

Materials (Basel). 2021 Oct 12;14(20):5998. doi: 10.3390/ma14205998.


DOI:10.3390/ma14205998
PMID:34683592
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC8537208/
Abstract

The construction of superhydrophobic surfaces necessitates the rational design of topographic surface structure and the reduction of surface energy. To date, the reported strategies are usually complex with multi-steps and costly. Thus, the simultaneous achievement of the two indispensable factors is highly desired, yet rather challenging. Herein, we develop a novel structure engineering strategy of realizing the fabrication of a functionally integrated device (FID) with a superhydrophobic surface via a one-step spraying method. Specifically, silica nanoparticles are used to control the surface roughness of the device, while polydimethylsiloxane is employed as the hydrophobic coating. Benefitting from the adopted superhydrophobicity, the as-fabricated FID exhibits a continuous, excellent oil-water separating performance (e.g., 92.5% separating efficiency) when coupled with a peristaltic pump. Notably, a smart design of incorporating a gas switch is adopted in this device, thereby effectively preventing water from entering the FID, realizing thorough oil collection, and avoiding secondary pollution. This work opens up an avenue for the design and development of the FID, accessible for rapid preparation and large-scale practical application.

摘要

超疏水表面的构建需要合理设计表面形貌结构并降低表面能。迄今为止,所报道的策略通常步骤复杂且成本高昂。因此,同时实现这两个不可或缺的因素是非常理想的,但颇具挑战性。在此,我们开发了一种新颖的结构工程策略,通过一步喷涂法实现具有超疏水表面的功能集成器件(FID)的制造。具体而言,二氧化硅纳米颗粒用于控制器件的表面粗糙度,而聚二甲基硅氧烷用作疏水涂层。受益于所采用的超疏水性,所制备的FID在与蠕动泵结合使用时表现出连续、优异的油水分离性能(例如,分离效率为92.5%)。值得注意的是,该器件采用了一种智能设计,即加入气体开关,从而有效防止水进入FID,实现彻底的油收集,并避免二次污染。这项工作为FID的设计和开发开辟了一条途径,便于快速制备和大规模实际应用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9315/8537208/e163bdd33da2/materials-14-05998-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9315/8537208/5cb131d14b7b/materials-14-05998-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9315/8537208/c341fb4145ac/materials-14-05998-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9315/8537208/0dee3ffb444a/materials-14-05998-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9315/8537208/e2918f252c9c/materials-14-05998-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9315/8537208/078ad34f9f28/materials-14-05998-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9315/8537208/e163bdd33da2/materials-14-05998-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9315/8537208/5cb131d14b7b/materials-14-05998-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9315/8537208/c341fb4145ac/materials-14-05998-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9315/8537208/0dee3ffb444a/materials-14-05998-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9315/8537208/e2918f252c9c/materials-14-05998-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9315/8537208/078ad34f9f28/materials-14-05998-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9315/8537208/e163bdd33da2/materials-14-05998-g006.jpg

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引用本文的文献

[1]
Construction of Superhydrophobic Coating on Iron Surface with Enhanced Anti-Corrosion, Anti-Adhesive and Anti-Bacterial Properties.

Materials (Basel). 2022-12-3

[2]
Atmospheric Pressure Plasma-Treated Polyurethane Foam as Reusable Absorbent for Removal of Oils and Organic Solvents from Water.

Materials (Basel). 2022-11-10

[3]
Facile Construction and Fabrication of a Superhydrophobic and Super Oleophilic Stainless Steel Mesh for Separation of Water and Oil.

Nanomaterials (Basel). 2022-5-13

本文引用的文献

[1]
A strategy for preparing controllable, superhydrophobic, strongly sticky surfaces using SiO@PVDF raspberry core-shell particles.

RSC Adv. 2021-7-5

[2]
On-site marine oil spillage monitoring probes formed by fixing oxygen sensors into hydrophobic/oleophilic porous materials for early-stage spotty pollution warning.

RSC Adv. 2021-6-15

[3]
Facile preparation of a superamphiphilic nitrocellulose membrane enabling on-demand and energy-efficient separation of oil/water mixtures and emulsions by prewetting.

Biomater Sci. 2021-8-21

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Highly efficient reusable superhydrophobic sponge prepared by a facile, simple and cost effective biomimetic bonding method for oil absorption.

Sci Rep. 2021-6-7

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Self-Formation of Superhydrophobic Surfaces through Interfacial Energy Engineering between Liquids and Particles.

Langmuir. 2021-5-4

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Elastic-Modulus-Dependent Macroscopic Supramolecular Assembly of Poly(dimethylsiloxane) for Understanding Fast Interfacial Adhesion.

Langmuir. 2021-4-13

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Rational design of materials interface at nanoscale towards intelligent oil-water separation.

Nanoscale Horiz. 2018-5-1

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Superhydrophobic Methylated Silica Sol for Effective Oil-Water Separation.

Materials (Basel). 2020-2-13

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Superhydrophobic Polyurethane Foam Coated with Polysiloxane-Modified Clay Nanotubes for Efficient and Recyclable Oil Absorption.

ACS Appl Mater Interfaces. 2019-7-17

[10]
Mini-Generator Based on Reciprocating Vertical Motions Driven by Intracorporeal Energy.

Adv Healthc Mater. 2019-3-12

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