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监测马来西亚河口水体和沉积物中直链烷基苯(LABs)的分布。

Monitoring of linear alkyl benzenes (LABs) in riverine and estuarine sediments in Malaysia.

机构信息

Department of Marine Chemistry and Pollution, Faculty of Marine Science and Environment, Hodeidah University, Hodeidah City, Yemen.

Department of Chemistry, College of Science, University of Hail, Hail City, Saudi Arabia.

出版信息

Environ Geochem Health. 2022 Oct;44(10):3687-3702. doi: 10.1007/s10653-021-01088-6. Epub 2021 Oct 25.

Abstract

The aim of this a pioneering research is to investigate linear alkylbenzenes (LABs) as biomarkers of sewage pollution in sediments collected from four rivers and estuaries of the south and east of Peninsular Malaysia. The sediment samples went through soxhlet extraction, two-step column chromatography purification, fractionation and gas chromatography-mass spectrometry (GC-MS) analysis. Principal component analysis (PCA) with multivariate linear regression (MLR) was used as well for source apportionment of LABs. The results of this study showed that total LAB concentration was 36-1196 ng gdw. The internal to external isomer ratios (I/E ratio) of LABs were from 0.56 to 3.12 indicated release of raw sewage and primary and secondary effluents into the environment of south and east of Peninsular Malaysia. Our research supported that continuous monitoring of sewage pollution to limit the environmental pollution in riverine and estuarine ecosystem.

摘要

本研究旨在探讨从马来西亚半岛南部和东部的四条河流和河口采集的沉积物中作为污水污染生物标志物的直链烷基苯 (LAB)。对沉积物样品进行索氏提取、两步柱层析净化、分级和气相色谱-质谱 (GC-MS) 分析。还使用主成分分析 (PCA) 和多元线性回归 (MLR) 对 LAB 的来源进行了分配。本研究结果表明,总 LAB 浓度为 36-1196nggdw。LAB 的内-外异构体比值 (I/E 比值) 为 0.56 至 3.12,表明原始污水以及初级和二级废水已排放到马来西亚半岛南部和东部的环境中。我们的研究支持对污水污染进行持续监测,以限制河口水生态系统的环境污染。

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