Enhancement of membrane fouling mitigation and trace organic compounds removal by electric field in a microfiltration reactor treating secondary effluent of a municipal wastewater treatment plant.

Applying an electric field in the membrane filtration was an effective method to alleviate membrane fouling and enhance the trace organic compounds (TrOCs) removal. The secondary effluent of a municipal wastewater treatment plant was used as feed water to evaluate the performance of the electric field coupled microfiltration system. Applying a 1.25 V voltage reduced 22.9% membrane fouling by electrophoretic force, and the membrane fouling was alleviated by 70.8% at 3 V by electrochemical oxidation and electric field force. At 3 V, active chlorine and hydroperoxide generated on the electrodes and the acidic environment formed around the anode significantly inhibited the growth of microorganisms and their attachment on the membrane surface, and thus reduced the membrane fouling formed by microorganisms. Electrochemical oxidation also removed the protein in wastewater and changed the main organic components of membrane fouling from microorganisms, protein, and polysaccharide to humic substances and polysaccharide. Furthermore, the electrophoretic force and acidic environment reduced the electrostatic repulsion of humic substances and made them tend to aggregate and form hydrophilic porous fouling structures, which obviously lowered filtration resistance and showed significant membrane fouling mitigation. Also, the electric field effectively enhanced the removal of target TrOCs through electrochemical oxidation and electric field force improving the elimination of TrOCs from 8.5% ~ 26.1% at 0 V to 35.9% ~ 84.8% at 3 V.