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具有增强光催化降解黄曲霉毒素B1性能的可回收氧化石墨烯/金属有机骨架材料/氧化亚铁杂化纳米复合材料的合成

Synthesis of recyclable GO/Cu(BTC)/FeO hybrid nanocomposites with enhanced photocatalytic degradation of aflatoxin B1.

作者信息

Samuel Melvin S, Mohanraj K, Chandrasekar Narendhar, Balaji Ramachandran, Selvarajan Ethiraj

机构信息

School of Environmental Science and Engineering, Indian Institute of Technology, Kharagpur, West Bengal, 731 302, India.

Department of Environmental Engineering and Management, Chaoyang University of Technology, Taichung, 41349, Taiwan.

出版信息

Chemosphere. 2022 Mar;291(Pt 2):132684. doi: 10.1016/j.chemosphere.2021.132684. Epub 2021 Oct 27.

Abstract

This study evaluated the photocatalytic performance of the activated carbon assisted GO/Cu(BTC)/FeO photocatalyst for aflatoxin B1 (AFB1) degradation under ultraviolet light. The nanocomposite was characterized by Fourier transform infrared spectrometry (FTIR), X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and nitrogen adsorption-desorption. The numerous factors influencing the degradation efficiency of AFB1 including catalyst dose, pH importance, and contact time were also probed. The elevated degradation performance of AFB1 by 99% was due to a larger surface area and improved GO/Cu(BTC)/FeO photocatalyst. The degradation process followed a pseudo-first-order kinetic model. Moreover, it is possible to quickly isolate the catalyst from the solution and retain successful operation. In the degradation of AFB1, the hole(h) and the hydroxyl radicals(OH) were found to play a significant role. These studies showed that GO/Cu(BTC)/FeO has high capturing capacity and photoactivity synergy, thereby offering a quick effect, and green solution to AFB1 degradation.

摘要

本研究评估了活性炭辅助的GO/Cu(BTC)/FeO光催化剂在紫外光下对黄曲霉毒素B1(AFB1)的光催化降解性能。通过傅里叶变换红外光谱(FTIR)、X射线衍射(XRD)、扫描电子显微镜(SEM)、透射电子显微镜(TEM)和氮吸附-脱附对该纳米复合材料进行了表征。还探究了影响AFB1降解效率的众多因素,包括催化剂用量、pH值的重要性和接触时间。AFB1降解性能提高99%归因于更大的表面积和改进的GO/Cu(BTC)/FeO光催化剂。降解过程遵循准一级动力学模型。此外,能够快速从溶液中分离出催化剂并保持成功运行。在AFB1的降解中,发现空穴(h)和羟基自由基(OH)起重要作用。这些研究表明,GO/Cu(BTC)/FeO具有高捕获能力和光活性协同作用,从而为AFB1降解提供了快速有效的绿色解决方案。

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