重新审视六氟铱酸钠：电子、量子及相关材料的潜在前驱体
Revisiting Sodium Hexafluoroiridates: Perspective Precursors for Electronic, Quantum, and Related Materials.
作者信息
Gubanov Alexander I, Smolentsev Anton I, Filatov Evgeny, Kuratieva Natalia V, Danilenko Andrey M, Korenev Sergey Vasilievich
机构信息
Nikolaev Institute of Inorganic Chemistry, Siberian Branch Russian Academy of Science, 3, Acad. Lavrentiev Ave., Novosibirsk 630090, Russian Federation.
Novosibirsk State University, 1, Pirogova str., Novosibirsk 630090, Russian Federation.
出版信息
ACS Omega. 2021 Oct 14;6(42):27697-27701. doi: 10.1021/acsomega.1c02722. eCollection 2021 Oct 26.
The following salts have been synthesized and structurally characterized: Na[IrF]·2HO (2/, = 6.6327(4), = 10.0740(6), = 5.9283(5) Å, β = 122.3880(10)°) and Na[IrF]·2HO (-3, = 7.5963(3), = 7.5963(3), = 9.8056(4) Å) (for the first time) by single-crystal X-ray diffraction; the unit cell parameters of a tetragonal phase ( /, = 5.005(2), = 10.074(4) Å) of the stable α-Na[IrF] were determined for the first time; and the unit cell parameters of β-Na[IrF] (321, = 9.332(4), = 5.136(2) Å) and Na[IrF] (2/, = 5.567(4), = 5.778(4), = 8.017(2) Å, β = 90.41(2)°) were determined using powder X-ray diffraction (PXRD). The data of the thermal stability was obtained by differential thermal analysis (DTA) for all substances. The presence of Na[IrF]·HO monohydrate is predicted. H[IrF] was prepared in a solution and was demonstrated to behave as a strong dibasic acid.
已合成并通过结构表征了以下盐类
通过单晶X射线衍射首次得到Na[IrF]·2H₂O（单斜晶系，a = 6.6327(4)，b = 10.0740(6)，c = 5.9283(5) Å，β = 122.3880(10)°）和Na[IrF]·2H₂O（立方晶系，a = 7.5963(3)，b = 7.5963(3)，c = 9.8056(4) Å）；首次测定了稳定的α-Na[IrF]四方相（P4/nmm，a = 5.005(2)，c = 10.0,74(4) Å）的晶胞参数；使用粉末X射线衍射（PXRD）测定了β-Na[IrF]（P321，a = 9.332(4)，c = 5.136(2) Å）和Na[IrF]（单斜晶系，a = 5.567(4)，b = 5.778(4)，c = 8.017(2) Å，β = 90.41(2)°）的晶胞参数。通过差示热分析（DTA）获得了所有物质的热稳定性数据。预测存在Na[IrF]·H₂O一水合物。在溶液中制备了H[IrF]，并证明其表现为一种强二元酸。
Zotero 插件