Stasyuk A J, Stasyuk O A, Solà M, Voityuk A A
Institut de Química Computacional and Departament de Química, Universitat de Girona, C/ Maria Aurèlia Capmany 69, 17003 Girona, Catalonia, Spain.
Faculty of Chemistry, University of Warsaw, Pasteura 1, 02-093 Warsaw, Poland.
Dalton Trans. 2021 Nov 16;50(44):16214-16222. doi: 10.1039/d1dt02034j.
Investigation of photoinduced electron transfer (PET) in a series of experimentally reported complexes of fullerene with phosphangulene oxides shows that the replacement of O atoms in the bridge of phosphangulene with S atoms promotes efficient and ultrafast ET from phosphangulene oxide to fullerene in PGOOSS⊃C60 and PGOSSS⊃C60 complexes. The results obtained can be useful for the development of photovoltaic devices based on phosphangulenes.
对一系列实验报道的富勒烯与氧化膦烯配合物中的光致电子转移（PET）进行研究表明，在氧化膦烯的桥连中用硫原子取代氧原子可促进PGOOSS⊃C60和PGOSSS⊃C60配合物中从氧化膦烯到富勒烯的高效且超快的电子转移。所得结果可能对基于膦烯的光伏器件的开发有用。
