Department of Physics, University of Gujrat, 50700, Gujrat, Pakistan.
J Nanosci Nanotechnol. 2021 Jun 1;21(6):3573-3579. doi: 10.1166/jnn.2021.19015.
High demand of food for rapidly increasing population requires novel but ecofriendly fertilizers. Green reducing and capping agents are being explored to minimize production cost and toxicity of chemicals in synthesis of nanoparticles (NPs) which could be used to increase the production of crops and plants. In present research, Zinc Oxide Nanoparticles (ZnO NPs) are produced by employing an eco-friendly, simple and efficient green route using peel extract of . The optical properties of green synthesized ZnO NPs are explored by UV-Visible and Photoluminance spectroscopies where NPs presented 3.21 to 3.13 eV band gap. The morphology and purity of the ZnO NPs are analyzed by scanning electron microscopy (SEM), X-ray diffraction technique (XRD) and energy dispersive X-ray spectroscopy (EDX), respectively. The spherical like ZnO NPs having 23-90 nm size exhibited hexagonal structure with 8.89 to 8.62 nm crystallite size. Fourier transform infrared spectroscopy (FTIR) explores the existence of specific functional groups which are responsible for stabilization, capping and reduction during synthesis of nanoparticles. The green synthesized ZnO NPs are tested for seed germination of (black mustard) seeds at standard temperature and pressure. The activity shows that germination percentage of the seeds is enhanced 100% and seedling vigor index 16.45 after treatment with ZnO NPs and can be controlled by the concentration of NPs. Therefore, it can be expected that ZnO NPs can serve as the cost effective and ecofriendly nano-fertilizers in agriculture.
快速增长的人口对食物的高需求要求新型的、环保的肥料。正在探索绿色还原剂和封端剂,以最大限度地降低纳米颗粒(NPs)合成过程中化学品的生产成本和毒性,这些 NPs 可用于增加作物和植物的产量。在本研究中,采用一种环保、简单、高效的绿色路线,使用 的果皮提取物来制备氧化锌纳米粒子(ZnO NPs)。通过紫外-可见分光光度法和光致发光光谱法研究了绿色合成 ZnO NPs 的光学性质,其中 NPs 呈现出 3.21 至 3.13 eV 的带隙。通过扫描电子显微镜(SEM)、X 射线衍射技术(XRD)和能谱分析(EDX)分别分析了 ZnO NPs 的形貌和纯度。所制备的 ZnO NPs 呈球形,粒径为 23-90nm,具有六方结构,晶粒尺寸为 8.89 至 8.62nm。傅里叶变换红外光谱(FTIR)探讨了在纳米粒子合成过程中稳定、封端和还原作用的特定官能团的存在。将绿色合成的 ZnO NPs 用于在标准温度和压力下对 (黑芥菜)种子进行发芽试验。活性表明,用 ZnO NPs 处理后,种子的发芽率提高了 100%,幼苗活力指数达到 16.45,可以通过 NPs 的浓度来控制。因此,可以预期 ZnO NPs 可以作为农业中具有成本效益和环保的纳米肥料。