Mizelli-Ojdanic Andrea, Horky Jelena, Mingler Bernhard, Fanetti Mattia, Gardonio Sandra, Valant Matjaz, Sulkowski Bartosz, Schafler Erhard, Orlov Dmytro, Zehetbauer Michael J
Physics of Nanostructured Materials, Faculty of Physics, University of Vienna, 1090 Vienna, Austria.
Faculty of Industrial Engineering, University of Applied Sciences-Technikum Wien, 1200 Vienna, Austria.
Materials (Basel). 2021 Oct 25;14(21):6399. doi: 10.3390/ma14216399.
In this study, several biodegradable Mg alloys (Mg5Zn, Mg5Zn0.3Ca, Mg5Zn0.15Ca, and Mg5Zn0.15Ca0.15Zr, numbers in wt%) were investigated after thermomechanical processing via high-pressure torsion (HPT) at elevated temperature as well as after additional heat treatments. Indirect and direct analyses of microstructure revealed that the significant strength increases arise not only from dislocations and precipitates but also from vacancy agglomerates. By contrast with former low-temperature processing routes applied by the authors, a significant ductility was obtained because of temperature-induced dynamic recovery. The low initial values of Young's modulus were not significantly affected by warm HPT-processing. nor by heat treatments afterwards. Also, corrosion resistance did not change or even increase during those treatments. Altogether, the study reveals a viable processing route for the optimization of Mg alloys to provide enhanced mechanical properties while leaving the corrosion properties unaffected, suggesting it for the use as biodegradable implant material.
在本研究中,对几种可生物降解镁合金(Mg5Zn、Mg5Zn0.3Ca、Mg5Zn0.15Ca和Mg5Zn0.15Ca0.15Zr,重量百分比数值)在高温下通过高压扭转(HPT)进行热机械加工后以及进行额外热处理后进行了研究。对微观结构的间接和直接分析表明,显著的强度增加不仅源于位错和析出物,还源于空位团聚体。与作者之前采用的低温加工路线相比,由于温度诱导的动态回复,获得了显著的延展性。杨氏模量的低初始值不受热HPT加工的显著影响,也不受随后热处理的显著影响。此外,在这些处理过程中,耐腐蚀性没有改变甚至有所提高。总体而言,该研究揭示了一种可行的加工路线,用于优化镁合金以提供增强的机械性能,同时不影响其腐蚀性能,表明其可作为可生物降解植入材料使用。