在环境条件下，通过光诱导由醇、甲醇和一氧化碳合成不对称有机碳酸酯。
Light-induced synthesis of unsymmetrical organic carbonates from alcohols, methanol and CO under ambient conditions.
作者信息
Saini Sandhya, Gour Nand Kishor, Khan Shafiur Rehman, Deka Ramesh Chandra, Jain Suman L
机构信息
Chemical & Material Sciences Division, CSIR-Indian Institute of Petroleum, Haridwar Road, Mohkampur, Dehradun-248005, India.
Academy of Scientific and Innovative Research, Ghaziabad-201002, India.
出版信息
Chem Commun (Camb). 2021 Nov 30;57(95):12800-12803. doi: 10.1039/d1cc05833a.
The present work describes the first visible light-assisted, metal-free and organic base 1,1,3,3-tetramethyl guanidine (TMG) mediated synthesis of unsymmetrical methyl aryl/alkyl carbonates from the reaction of alcohols, methanol, and CO in high to excellent yields under atmospheric pressure and ambient temperature conditions.
本工作描述了首例可见光辅助、无金属且由有机碱1,1,3,3-四甲基胍（TMG）介导的反应，该反应可在常压和环境温度条件下，通过醇、甲醇与CO反应，以高至优异的产率合成不对称芳基/烷基碳酸甲酯。
Zotero 插件