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干基和湿基催化二氧化硫(SO)还原技术综述。

A review on dry-based and wet-based catalytic sulphur dioxide (SO) reduction technologies.

机构信息

Department of Chemical Engineering, Ming Chi University of Technology, New Taipei City 24301, Taiwan.

School of Energy and Chemical Engineering, Xiamen University Malaysia, Jalan Sunsuria, Bandar Sunsuria, 43900 Sepang, Selangor Darul Ehsan, Malaysia; College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China.

出版信息

J Hazard Mater. 2022 Feb 5;423(Pt A):127061. doi: 10.1016/j.jhazmat.2021.127061. Epub 2021 Aug 30.

Abstract

While sulphur dioxide (SO) is known for its toxicity, numerous effective countermeasures were innovated to alleviate its hazards towards the environment. In particular, catalytic reduction is favoured for its potential in converting SO into harmless, yet marketable product, such as elemental sulphur. Therefore, current review summarises the critical findings in catalytic SO reduction, emphasising on both dry- and wet-based technology. As for the dry-based technology, knowledge related to SO reduction over metal-, rare earth- and carbon-based catalysts are summarised. Significantly, both the reduction mechanisms and important criteria for efficient SO reduction are elucidated too. Meanwhile, the wet-based SO reduction are typically conducted in reactive liquid medium, such as metal complexes, ionic liquids and organic solvents. Therefore, the applications of the aforesaid liquid mediums are discussed thoroughly in the similar manner to dry-technology. Additionally, the pros and cons of each type of catalyst are also presented to provide valuable insights to the pertinent researchers. Finally, some overlooked aspects in both dry- and wet-based SO reduction are identified, with potential solutions given too. With these insights, current review is anticipated to contribute towards practicality improvement of catalytic SO reduction, which in turn, protects the environment from SO pollution.

摘要

二氧化硫 (SO) 是众所周知的毒性物质,但人们创新性地开发了许多有效的应对措施来减轻其对环境的危害。特别是,催化还原因其将 SO 转化为无害且有市场价值的产品(如元素硫)的潜力而受到青睐。因此,本文总结了催化 SO 还原的关键发现,重点介绍了干法和湿法两种技术。对于干法技术,总结了金属、稀土和碳基催化剂上 SO 还原的相关知识。重要的是,还阐明了 SO 还原的还原机制和有效还原的重要标准。同时,湿法 SO 还原通常在反应性液体介质中进行,如金属配合物、离子液体和有机溶剂。因此,以类似的方式对上述液体介质的应用进行了彻底讨论。此外,还介绍了每种类型催化剂的优缺点,为相关研究人员提供了有价值的见解。最后,确定了干法和湿法 SO 还原中一些被忽视的方面,并给出了潜在的解决方案。通过这些见解,预计本综述将有助于提高催化 SO 还原的实用性,从而保护环境免受 SO 污染。

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