- 配位钌阳离子：苄胺和苄醇需氧氧化的高效催化剂。
,-coordinated Ru cation: a robust catalyst for aerobic oxidations of benzylamine and benzyl alcohol.
作者信息
Aman Michal, Dostál Libor, Růžička Aleš, Tydlitát Jiří, Beckmann Jens, Turek Jan, Jambor Roman
机构信息
Department of General and Inorganic Chemistry, University of Pardubice, 532 10 Pardubice, Czech Republic.
Institut für Anorganische Chemie und Kristallographie, Universität Bremen, Leobener Straße 7, 28359 Bremen, Germany.
出版信息
Chem Commun (Camb). 2021 Dec 3;57(96):12992-12995. doi: 10.1039/d1cc06173a.
A stable ionic κ,-coordinated Ru complex shows excellent catalytic activity in aerobic oxidations of benzylamine and benzyl alcohol. This complex is stabilized by a stannylene-phosphine -substituted naphthalene ligand, which can act as either a reducing agent for a Ru(III) complex or as a κ,-chelating ligand for Ru(II) compounds.
一种稳定的离子κ-配位钌配合物在苄胺和苄醇的需氧氧化反应中表现出优异的催化活性。该配合物由亚甲锡基膦取代的萘配体稳定，该配体既可以作为Ru(III)配合物的还原剂，也可以作为Ru(II)化合物的κ-螯合配体。
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