Ultrafine and well-dispersed Pd-Ni bimetallic catalyst stabilized by dendrimer-grafted magnetic graphene oxide for selective reduction of toxic nitroarenes under mild conditions.

A facile and efficient strategy is introduced for growing a dendrimer structure on the surface of magnetic graphene oxide by using thiol-ene click reaction. The as-synthesized dendrimer-grafted magnetic graphene oxide was used as a suitable support for bimetallic Pd-Ni nanoparticles. The prepared nanocomposite was utilized for the reduction of toxic nitroarenes to aminoarenes by using sodium borohydride in aqueous medium at room temperature. Various nitroarenes with functional groups like nitrile, halogen, carbonyl, hydroxyl, acid, and heterocycles were converted to their corresponding anilines with good to excellent yields. The enhanced performance of the catalyst could be attributed to the synergistic effect between Ni and Pd which causes the reaction to proceed more efficiently. Moreover, the catalyst could be readily isolated from the reaction mixture by utilizing an external magnet and reused till 5th cycles with marginal loss of activity.