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基于残差网络的激光诱导击穿光谱法提高塑料分类的准确性

Accuracy improvement in plastics classification by laser-induced breakdown spectroscopy based on a residual network.

作者信息

Peng Xinying, Xu Bohan, Xu Zhiying, Yan Xiaotao, Zhang Ning, Qin Yuzhi, Ma Qiongxiong, Li Jiaming, Zhao Nan, Zhang Qingmao

出版信息

Opt Express. 2021 Oct 11;29(21):33269-33280. doi: 10.1364/OE.438331.

DOI:10.1364/OE.438331
PMID:34809142
Abstract

The whole ecosystem is suffering from serious plastic pollution. Automatic and accurate classification is an essential process in plastic effective recycle. In this work, we proposed an accurate approach for plastics classification using a residual network based on laser-induced breakdown spectroscopy (LIBS). To increasing efficiency, the LIBS spectral data were compressed by peak searching algorithm based on continuous wavelet, then were transformed to characteristic images for training and validation of the residual network. Acrylonitrile butadiene styrene (ABS), polyamide (PA), polymethyl methacrylate (PMMA), and polyvinyl chloride (PVC) from 13 manufacturers were used. The accuracy of the proposed method in few-shot learning was evaluated. The results show that when the number of training image data was 1, the verification accuracy of classification by plastic type under residual network still kept 100%, which was much higher than conventional classification algorithms (BP, kNN and SVM). Furthermore, the training and testing data were separated from different manufacturers to evaluate the anti-interference properties of the proposed method from various additives in plastics, where 73.34% accuracy was obtained. To demonstrate the superiority of classification accuracy in the proposed method, all the evaluations were also implemented by using conventional classification algorithm (kNN, BP, SVM algorithm). The results confirmed that the residual network has a significantly higher accuracy in plastics classification and shows great potential in plastic recycle industries for pollution mitigation.

摘要

整个生态系统正遭受严重的塑料污染。自动且准确的分类是塑料有效回收的关键过程。在这项工作中,我们提出了一种基于激光诱导击穿光谱(LIBS)的残差网络用于塑料分类的精确方法。为了提高效率,利用基于连续小波的峰值搜索算法对LIBS光谱数据进行压缩,然后将其转换为特征图像用于残差网络的训练和验证。使用了来自13个制造商的丙烯腈-丁二烯-苯乙烯共聚物(ABS)、聚酰胺(PA)、聚甲基丙烯酸甲酯(PMMA)和聚氯乙烯(PVC)。评估了所提方法在少样本学习中的准确性。结果表明,当训练图像数据数量为1时,残差网络下按塑料类型分类的验证准确率仍保持100%,远高于传统分类算法(BP、kNN和SVM)。此外,将训练和测试数据分离自不同制造商,以评估所提方法对塑料中各种添加剂的抗干扰性能,获得了73.34%的准确率。为了证明所提方法在分类准确性方面的优越性,还使用传统分类算法(kNN、BP、SVM算法)进行了所有评估。结果证实,残差网络在塑料分类中具有显著更高的准确率,在塑料回收行业减轻污染方面显示出巨大潜力。

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