Facile synthesis of novel multifunctional β-cyclodextrin microporous organic network and application in efficient removal of bisphenol A from water.

Here, a novel multifunctional β-cyclodextrin microporous organic network (CD-MON) has been successfully synthesized and used to remove bisphenol A (BPA) from water. The morphology and composition of the synthesized CD-MON were confirmed. The combination of hydrophobic interaction, π-π interaction inclusion mechanism and hydrogen bonding endowed CD-MON to exhibit superior adsorption capacity toward BPA. The adsorption kinetics and isotherms of BPA and other four model aromatic pollutants on CD-MON were studied. CD-MON could maintain adsorption efficiency toward BPA over wide pH ranges and without being affected by the ionic strengths, co-existing inorganic ions and humic acid. The optimal conditions and removal efficiency of BPA were screened by response surface analysis. In addition, nearly unchanged in the adsorption efficiency toward BPA was observed after five regeneration cycles on CD-MON. CD-MON can adsorb about 80% of five model aromatic pollutants from the water within 40 s in the flow-through experiments. This novel adsorbent gives great promise for practical wastewater remediation.